所有图片(1)
About This Item
经验公式（希尔记法）:
C7H15NOSi
CAS号:
分子量:
157.29
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
检测方案
96%
折射率
n20/D 1.46 (lit.)
bp
90 °C/20 mmHg (lit.)
密度
0.983 g/mL at 25 °C (lit.)
SMILES字符串
C[Si](C)(C)N1CCCC1=O
InChI
1S/C7H15NOSi/c1-10(2,3)8-6-4-5-7(8)9/h4-6H2,1-3H3
InChI key
LUBVCBITQHEVCJ-UHFFFAOYSA-N
一般描述
1-(Trimethylsilyl)-2-pyrrolidinone has been prepared by refluxing a mixture of 2-pyrrolidinone, triethylamine and trimethylchlorosilane in benzene. It undergoes sulfenylation with phenyl disulfide to form the corresponding bissulfide as the major product.
应用
1-(Trimethylsilyl)-2-pyrrolidinone may be used for the preparation of 1-(diphenylphosphonio)pyrrolidin-2-one and 1-(1-adamantylcarbonyl)-2-pyrrolidinone.
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
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Synthesis and antiviral activity evaluation of some new aminoadamantane derivatives. 2.
Kolocouris N, et al.
Journal of Medicinal Chemistry, 39(17), 3307-3318 (1996)
Sulfenylation and sulfinylation of lactams and imino ethers.
Zoretic PA, et al.
The Journal of Organic Chemistry, 43(7), 1379-1382 (1978)
Efficient method for the preparation of carboxylic acid alkyl esters or alkyl phenyl ethers by a new-type of oxidation-reduction condensation using 2, 6-dimethyl-1, 4-benzoquinone and alkoxydiphenylphosphines.
Shintou T, et al.
Bulletin of the Chemical Society of Japan, 76(8), 1645-1667 (2003)
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