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方案
98%
折射率
n20/D 1.546 (lit.)
沸点
79-83 °C/0.3 mmHg (lit.)
密度
1.194 g/mL at 25 °C (lit.)
λmax
224 nm
SMILES字符串
COS(=O)c1ccccc1
InChI
1S/C7H8O2S/c1-9-10(8)7-5-3-2-4-6-7/h2-6H,1H3
InChI key
PSNSVDSRLUYDKF-UHFFFAOYSA-N
一般描述
Methyl benzenesulfinate is an ester of aromatic sulfinic acid. It reacts smoothly with thionyl chloride at room temperature to afford sulfinyl chloride and methyl chlorosulfonate.
应用
Methyl benzenesulfinate may be employed for the synthesis of symmetrical disulfides.
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
197.6 °F - closed cup
闪点(°C)
92 °C - closed cup
法规信息
新产品
Metathetical Reactions of Silver Salts in Solution. II. The Synthesis of Alkyl Sulfonates1.
Emmons WD and Ferris AF.
Journal of the American Chemical Society, 75(5), 2257-2257 (1953)
Reductive formation of disulfides from sulfenyl, sulfinyl, and sulfonyl derivatives using tri-n-propylamine and trichlorosilane.
Chan T-H, et al.
Journal of the American Chemical Society, 92(24), 7224-7225 (1970)
Derivatives of Aromatic Sulfinic Acids. II. The Reaction of Thionyl Chloride with Sulfinic Esters1, 2.
Herbrandson HF, et al.
Journal of the American Chemical Society, 78(11), 2576-2578 (1956)
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