458910
2-乙硫醇
97%
别名:
N-(2-巯乙基)氨基甲酸叔丁酯
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关于此项目
线性分子式:
HSCH2CH2NHCO2C(CH3)3
化学文摘社编号:
分子量:
177.26
UNSPSC Code:
12352105
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2243173
产品名称
2-乙硫醇, 97%
InChI
1S/C7H15NO2S/c1-7(2,3)10-6(9)8-4-5-11/h11H,4-5H2,1-3H3,(H,8,9)
SMILES string
SCCNC(OC(C)(C)C)=O
InChI key
GSJJCZSHYJNRPN-UHFFFAOYSA-N
assay
97%
reaction suitability
reagent type: cross-linking reagent
refractive index
n20/D 1.474 (lit.)
bp
68 °C/0.3 mmHg (lit.)
density
1.049 g/mL at 20 °C (lit.)
functional group
Boc
amine
thiol
Quality Level
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Application
2-Boc-氨基乙硫醇可用于引入胺官能团，用于通过巯基-烯点击化学反应对交联聚合物膜进行表面改性。也可参与巯基-烯反应，使polyglobalide(PGI)胺功能化。
General description
2-Boc-氨基乙硫醇又名N-(2-巯乙基)氨基甲酸叔丁酯，可用作各种有机合成反应的交联剂。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
228.2 °F - closed cup
flash_point_c
109 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Poly (amino acid)-grafted polymacrolactones. Synthesis, self-assembling and ionic coupling properties
E Tinajero-Diaz, et al.
Reactive and Functional Polymers, 143, 104316-104316 (2019)
Terpolymerization of propylene oxide and vinyl oxides with CO 2: copolymer cross-linking and surface modification via thiol-ene click chemistry.
DJ Darensbourg, et al.
Polym. Chem., 1768-1776 (2015)
T M Winger et al.
Bioconjugate chemistry, 6(3), 323-326 (1995-05-01)
The derivatization of poly(p-(chloromethyl)styrene-co-divinylbenzene) (Merrifield resin) with N-(tert-butoxycarbonyl)-2-aminoethanethiol is presented as a convenient route for the generation of thiol terminated peptides using a solid phase methodology. Maximum resin substitution reached 92% (773 mumol/g) after 24 h. However, at 30 min
Ernesto Tinajero-Díaz et al.
Polymers, 12(4) (2020-04-30)
The enzymatic ring-opening copolymerization (eROP) of globalide (Gl) and pentadecalactone (PDL) was performed in solution from mixtures of the two macrolactones at ratios covering the whole range of comonomeric compositions. The resulting P(Glx-r-PDLy) random copolyesters were aminofunctionalized by thiol-ene reaction
Louise Stjern et al.
International journal of pharmaceutics, 531(2), 595-605 (2017-05-31)
Cyclodextrins (CDs) and mesoporous silica particles (MSPs) have been combined as composite carriers for controlled antibiotic release. CDs were employed as "gatekeeper" agents and grafted onto MSPs to retain drug molecules inside the MSP carrier. A variety of CDs (unfunctionalized
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