456055
莰烯
95%
别名:
(±)-莰烯, 2,2-二甲基-3-亚甲基双环[2.2.1]庚烷, 2,2-二甲基-3-亚甲基降冰片烷, 2,2-二甲基-3-甲亚基双环[2.2.1]庚烷, 2-亚甲基-3,3-二甲基双环[2.2.1]庚烷, 3,3-二甲基-2-亚甲基降冰片烷, 3,3-二甲基-2-亚甲基降莰烷, DL-莰烯
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关于此项目
经验公式（希尔记法）:
C10H16
化学文摘社编号:
分子量:
136.23
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
95%
表单
solid
沸点
159-160 °C (lit.)
mp
48-52 °C (lit.)
密度
0.85 g/mL at 25 °C (lit.)
SMILES字符串
[H][C@]12CC[C@]([H])(C1)C(C)(C)C2=C
InChI
1S/C10H16/c1-7-8-4-5-9(6-8)10(7,2)3/h8-9H,1,4-6H2,2-3H3/t8-,9+/m0/s1
InChI key
CRPUJAZIXJMDBK-DTWKUNHWSA-N
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一般描述
莰烯是双环单萜，是多种植物精油中的成分，包括月桃(Alpinia speciosa)、苍耳(Xanthium strumarium)叶、山松Pinus uncinata和Pinus uliginosa的松针。(5)
应用
莰烯作为反应剂的用途如下：
- 通过二氧化硅负载磷钨酸催化的C2-C6脂肪酸液相酯化反应合成异冰片基羧酸酯。
- 过氧化双月桂酰为引发剂，与N-羟基邻苯二甲酰亚胺和亚磷酸三乙酯通过分子间反马氏(anti-Markovnikov)氢胺化反应合成氢胺化莰烯。
- H2O2为氧化剂，吡唑为路易斯碱加合物，通过甲基三氧化铼催化的环氧化反应合成莰烯氧化物。
- 与醇通过阳离子交换树脂催化的烷氧化反应合成异冰片基烷醚。
警示用语：
Danger
危险声明
危险分类
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Sol. 1
储存分类代码
4.1B - Flammable solid hazardous materials
WGK
WGK 2
闪点(°F)
78.8 °F - DIN 51755 Part 1
闪点(°C)
26 °C - DIN 51755 Part 1
个人防护装备
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Radosław Bonikowski et al.
Natural product communications, 10(2), 371-373 (2015-04-30)
The compositions of mountain pine (Pinus uncinata) and peat-bog pine (P. uliginosa) needle essential oils were investigated. Enantiomeric compositions of selected monoterpene hydrocarbons were also examined. Respectively, fifty-three and seventy-six components of the essential oils were identified using GC-MS and
Dendritic growth kinetics and structure II. Camphene.
Rubinstein ER and Glicksman ME.
Journal of Crystal Growth, 112(1), 97-110 (1991)
Ioanna Vallianou et al.
PloS one, 6(11), e20516-e20516 (2011-11-11)
Central to the pathology of coronary heart disease is the accumulation of lipids, cholesterol and triglycerides, within the intima of arterial blood vessels. The search for drugs to treat dislipidemia, remains a major pharmaceutical focus. In this study, we evaluated
Xin Liu et al.
Acta biomaterialia, 8(1), 415-423 (2011-08-23)
Scaffolds of 13-93 bioactive glass (6Na(2)O, 12K(2)O, 5MgO, 20CaO, 4P(2)O(5), 53SiO(2); wt.%) with an oriented pore architecture were formed by unidirectional freezing of camphene-based suspensions, followed by thermal annealing of the frozen constructs to grow the camphene crystals. After sublimation
Patrick Giraudeau et al.
Journal of the American Chemical Society, 131(39), 13902-13903 (2009-09-12)
The combination of ex situ dynamic nuclear polarization (DNP) with nuclear magnetic resonance (NMR) leads to signal-to-noise enhancements of 10(3)-10(4) compared to conventional NMR. Ex situ DNP, however, is ill-suited for collecting the array of transients needed in 2D NMR
实验方案
-β-Farnesene; α-Huµlene; Germacrene D; (+)-Valencene; Bicyclogermacrene; (+)-δ-Cadinene
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