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质量水平
方案
95%
表单
solid
沸点
159-160 °C (lit.)
mp
48-52 °C (lit.)
密度
0.85 g/mL at 25 °C (lit.)
SMILES字符串
[H][C@]12CC[C@]([H])(C1)C(C)(C)C2=C
InChI
1S/C10H16/c1-7-8-4-5-9(6-8)10(7,2)3/h8-9H,1,4-6H2,2-3H3/t8-,9+/m0/s1
InChI key
CRPUJAZIXJMDBK-DTWKUNHWSA-N
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一般描述
莰烯是双环单萜，是多种植物精油中的成分，包括月桃(Alpinia speciosa)、苍耳(Xanthium strumarium)叶、山松Pinus uncinata和Pinus uliginosa的松针。(5)
应用
莰烯作为反应剂的用途如下：
- 通过二氧化硅负载磷钨酸催化的C2-C6脂肪酸液相酯化反应合成异冰片基羧酸酯。
- 过氧化双月桂酰为引发剂，与N-羟基邻苯二甲酰亚胺和亚磷酸三乙酯通过分子间反马氏(anti-Markovnikov)氢胺化反应合成氢胺化莰烯。
- H2O2为氧化剂，吡唑为路易斯碱加合物，通过甲基三氧化铼催化的环氧化反应合成莰烯氧化物。
- 与醇通过阳离子交换树脂催化的烷氧化反应合成异冰片基烷醚。
警示用语：
Danger
危险声明
危险分类
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Sol. 1
储存分类代码
4.1B - Flammable solid hazardous materials
WGK
WGK 2
闪点(°F)
78.8 °F - DIN 51755 Part 1
闪点(°C)
26 °C - DIN 51755 Part 1
个人防护装备
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Dendritic growth kinetics and structure II. Camphene.
Rubinstein ER and Glicksman ME.
Journal of Crystal Growth, 112(1), 97-110 (1991)
Radosław Bonikowski et al.
Natural product communications, 10(2), 371-373 (2015-04-30)
The compositions of mountain pine (Pinus uncinata) and peat-bog pine (P. uliginosa) needle essential oils were investigated. Enantiomeric compositions of selected monoterpene hydrocarbons were also examined. Respectively, fifty-three and seventy-six components of the essential oils were identified using GC-MS and
Javad Sharifi-Rad et al.
Molecules (Basel, Switzerland), 20(4), 7034-7047 (2015-04-22)
The chemical composition of the essential oil (EO) from fresh cocklebur (Xanthium strumarium L.) leaves was investigated by GC-MS. The antimicrobial activity of the EO was tested against Gram-positive and Gram-negative bacteria and fungi. Scolicidal activity was assayed against Echinococcus
M Tiwari et al.
Toxicology in vitro : an international journal published in association with BIBRA, 23(2), 295-301 (2009-01-13)
Exploration of antioxidants of plant origin and scientific validation of their efficacies has unraveled bioactives from natural sources. In this study, two terpenoids camphene and geraniol were assessed for their cytoprotective and antioxidant potential using t-BHP stressed rat alveolar macrophages.
A Sunesson et al.
Applied and environmental microbiology, 61(8), 2911-2918 (1995-08-01)
Five fungal species, Aspergillus versicolor, Penicillium commune, Cladosporium cladosporioides, Paecilomyces variotii, and Phialophora fastigiata, were cultivated on two media, malt extract agar and dichloran glycerol agar. Culture flasks provided with inlet and outlet tubes were used and purified, and humidified
实验方案
-β-Farnesene; α-Huµlene; Germacrene D; (+)-Valencene; Bicyclogermacrene; (+)-δ-Cadinene
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