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Merck
CN
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文件

安全信息

456055

Sigma-Aldrich

莰烯

95%

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别名:
(±)-Camphene, 2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane, 2,2-Dimethyl-3-methylenenorbornane, 2,2-Dimethyl-3-methylidenebicyclo[2.2.1]heptane, 2-Methylene-3,3-dimethylbicyclo[2.2.1]heptane, 3,3-Dimethyl-2-methylenenorbornane, 3,3-Dimethyl-2-methylenenorcamphane, DL-Camphene
经验公式（希尔记法）:
C10H16
CAS号:
79-92-5
分子量:
136.23
EC 号:
201-234-8
MDL编号:
MFCD00066603
UNSPSC代码:
12352100
PubChem化学物质编号:
24869106
NACRES:
NA.22

质量水平

100

检测方案

95%

形式

solid

bp

159-160 °C (lit.)

mp

48-52 °C (lit.)

密度

0.85 g/mL at 25 °C (lit.)

SMILES字符串

[H][C@]12CC[C@]([H])(C1)C(C)(C)C2=C

InChI

1S/C10H16/c1-7-8-4-5-9(6-8)10(7,2)3/h8-9H,1,4-6H2,2-3H3/t8-,9+/m0/s1

InChI key

CRPUJAZIXJMDBK-DTWKUNHWSA-N

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相关类别

一般描述

莰烯是双环单萜，是多种植物精油中的成分，包括月桃(Alpinia speciosa)、苍耳(Xanthium strumarium)叶、山松Pinus uncinata和Pinus uliginosa的松针。(5)

应用

莰烯作为反应剂的用途如下：
  • 通过二氧化硅负载磷钨酸催化的C2-C6脂肪酸液相酯化反应合成异冰片基羧酸酯。
  • 过氧化双月桂酰为引发剂，与N-羟基邻苯二甲酰亚胺和亚磷酸三乙酯通过分子间反马氏(anti-Markovnikov)氢胺化反应合成氢胺化莰烯。
  • H2O2为氧化剂，吡唑为路易斯碱加合物，通过甲基三氧化铼催化的环氧化反应合成莰烯氧化物。
  • 与醇通过阳离子交换树脂催化的烷氧化反应合成异冰片基烷醚。

警示用语：

Danger

危险声明

H228,H319,H410

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Sol. 1

WGK

WGK 2

闪点(°F)

DIN 51755 Part 1

闪点(°C)

DIN 51755 Part 1

个人防护装备

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品

分析证书(COA)

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Radosław Bonikowski et al.
Natural product communications, 10(2), 371-373 (2015-04-30)
The compositions of mountain pine (Pinus uncinata) and peat-bog pine (P. uliginosa) needle essential oils were investigated. Enantiomeric compositions of selected monoterpene hydrocarbons were also examined. Respectively, fifty-three and seventy-six components of the essential oils were identified using GC-MS and
Dendritic growth kinetics and structure II. Camphene.
Rubinstein ER and Glicksman ME.
Journal of Crystal Growth, 112(1), 97-110 (1991)
Magdalena Ceborska et al.
Carbohydrate polymers, 91(1), 110-114 (2012-10-10)
The separation of isomeric monoterpenes, camphene and fenchene by complexation with β-cyclodextrin is presented. Both of the monoterpenes form complexes with β-cyclodextrin (as shown by both gas chromatography and (1)H NMR) with similar stability constants nevertheless it is possible to
Seok-Jung Hong et al.
Macromolecular bioscience, 9(7), 639-645 (2009-02-20)
PCL microspheres featuring a macroporous morphology and a bone-bioactive surface have been prepared. 'Camphene' was introduced to generate pores within the microsphere network. The pore size was variable from a few to tens to hundreds of microm depending on the
Young J Hong et al.
Organic & biomolecular chemistry, 8(20), 4589-4600 (2010-08-21)
Based on quantum chemical studies, mechanisms to form bornyl diphosphate from geranyl diphosphate are suggested. While bornyl diphosphate is usually proposed to be generated via combination of the pyrophosphate group with a secondary bornyl cation, quantum chemical computations indicate that
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实验方案

GC Analysis of Sweet Orange Essential Oil on SLB®-5ms (10 m x 0.10 mm I.D., 0.10 µm), Fast GC Analysis

-β-Farnesene; α-Huµlene; Germacrene D; (+)-Valencene; Bicyclogermacrene; (+)-δ-Cadinene

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