包含
BHT as stabilizer
质量水平
bp
170 °C (lit.)
mp
33 °C (lit.)
密度
0.986 g/mL at 25 °C (lit.)
SMILES字符串
C1C=CC2C3CC(C=C3)C12
InChI
1S/C10H12/c1-2-9-7-4-5-8(6-7)10(9)3-1/h1-2,4-5,7-10H,3,6H2/t7-,8+,9?,10?/m0/s1
InChI key
HECLRDQVFMWTQS-AFWXGSBKSA-N
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一般描述
双环戊二烯(DCPD)是环戊二烯的二聚体,由两个不饱和双键组成(一个在降冰片烯环上,一个在环戊烯环上)。DCPT 可单独用于聚合物中,也可与其他碳氢化合物一起使用。它也用于制药、弹性体、聚碳酸酯和聚酯树脂。
应用
双环戊二烯可用于:
- 采用 VARTM(真空辅助树脂转移模塑)工艺制备 CF/p-DCPD(碳纤维/聚双环戊二烯)复合材料。
- 在 η5-环戊二烯基三(二甲基氨基)锆催化剂的制备中。
- 在纤维素–马来酸酐–双环戊二烯共聚物基体的自由基聚合合成中。
特点和优势
DCPD 与邻苯二甲酸和间苯二甲酸聚酯相比具有以下优点:
- 低收缩率
- 降低成本效益
- 减少苯乙烯的排放
- 薄层快速固化
警示用语:
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
ACS applied materials & interfaces, 6(21), 19075-19081 (2014-10-22)
Zinc(II) oxide nanoparticles were used for the stabilization of dicyclopentadiene (DCPD)-water-based high internal phase emulsions (HIPEs), which were subsequently cured using ring-opening metathesis polymerization (ROMP). The morphology of the resulting ZnO-pDCPD nanocomposite foams was investigated in correlation to the nanoparticle
Frontal ring-opening metathesis polymerization of dicyclopentadiene.
Macromolecules, 34(19), 6539-6541 (2001)
Morphological and mechanical evaluation of hybrid organic-inorganic thermoset copolymers of dicyclopentadiene and mono-or tris (norbornenyl)-substituted polyhedral oligomeric silsesquioxanes.
Macromolecules, 37(4), 1276-1282 (2004)
Chemistry (Weinheim an der Bergstrasse, Germany), 20(43), 14120-14125 (2014-09-11)
Cyclic Ru-phenolates were synthesized, and these compounds were used as olefin metathesis catalysts. Investigation of their catalytic activity pointed out that, after activation with chemical agents, these catalysts promote ring-closing metathesis (RCM), enyne and cross-metathesis (CM) reactions, including butenolysis, with
Journal of the American Chemical Society, 141(34), 13619-13624 (2019-08-08)
Herein, we report the development of a scalable and synthetically robust building block based on norbornadiene (NBD) that can be broadly incorporated into a variety of macromolecular architectures using traditional living polymerization techniques. By taking advantage of a selective and
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MOST offers controlled solar energy harvesting and storage, addressing global energy demands with improved storage techniques.
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