所有图片(1)
About This Item
经验公式（希尔记法）:
C22H20O2
CAS号:
分子量:
316.39
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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方案
98%
表单
solid
旋光性
[α]20/D +10.5°, c = 1 in chloroform
光学纯度
ee: 98% (GLC)
mp
99-102 °C (lit.)
SMILES字符串
C1O[C@H]1COC(c2ccccc2)(c3ccccc3)c4ccccc4
InChI
1S/C22H20O2/c1-4-10-18(11-5-1)22(24-17-21-16-23-21,19-12-6-2-7-13-19)20-14-8-3-9-15-20/h1-15,21H,16-17H2/t21-/m1/s1
InChI key
XFSXUCMYFWZRAF-OAQYLSRUSA-N
应用
近期已通过分别用胞嘧啶衍生物、胺和硫醇使该环氧化物开环，制备具有抗单纯疱疹病毒 1 和 2 活性的核苷酸、铵盐脂质体以及磷脂的硫代类似物。
(R)-(+)-Glycidyl trityl ether may be used in the preparation of (R)-trityl(thiiranylmethyl)ether by reacting with thiourea. It may also be used as a starting material in the multi-step synthesis of (+)-actisonitrile.
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
Bennett, M.J. et al.
Tetrahedron Letters, 36, 2207-2207 (1995)
Lin, H.-K. Gelb, M.H.
Journal of the American Chemical Society, 115, 3932-3932 (1993)
Brodfuehrer, P.R. et al.
Tetrahedron Letters, 35, 3243-3243 (1994)
Synthesis of aminoethanethiol trityl ether ligands for ruthenium-catalysed asymmetric transfer hydrogenation.
Harfouche J, et al.
Tetrahedron Letters, 15(21), 3413-3418 (2004)
Structure and synthesis of a unique isonitrile lipid isolated from the marine mollusk Actinocyclus papillatus.
Manzo E, et al.
Organic Letters, 13(8), 1897-1899 (2011)
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