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Merck
CN

452912

Sigma-Aldrich

氢化钠

greener alternative

60 % dispersion in mineral oil

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别名:
Sodium monohydride
线性分子式:
NaH
CAS号:
分子量:
24.00
MDL编号:
UNSPSC代码:
26111700
PubChem化学物质编号:
NACRES:
NA.22

形式

powder (moist, paste-like)

质量水平

反应适用性

reagent type: reductant

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

浓度

60 % dispersion in mineral oil

mp

800 °C (dec.) (lit.)

环保替代产品分类

SMILES字符串

[Na]

InChI

1S/Na.H

InChI key

MPMYQQHEHYDOCL-UHFFFAOYSA-N

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一般描述

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应用

氢化钠(NaH,矿物油中60%的分散成分)可以用于多种应用,如:
  • 制备增塑剂,形成用于光电应用的固体聚合物电解质(SPE)
  • 合成治疗化合物常见的成分杂芳基硫醚
  • 制备储氢材料氢化铝钠(NaAlH4)(3)
  • 用作醇、酚、酰胺、酮和不同官能团脱质子化的碱和还原剂(4)
  • 可能用于热能储存(5)

直接嵌入 C60 可得到超导材料 (NaH)4C60

象形图

FlameCorrosion

警示用语:

Danger

危险分类

Eye Dam. 1 - Flam. Sol. 1 - Met. Corr. 1 - Skin Corr. 1A - Water-react 1

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

监管及禁止进口产品

分析证书(COA)

输入产品批号来搜索 分析证书(COA) 。批号可以在产品标签上"批“ (Lot或Batch)字后找到。

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. What is the particle size of Product 452912, Sodium hydride in Mineral Oil? 

    Particle size is not one of our specifications so we have not tested for it and neither has the vendor. According to literature though, the particle size could range from 5 - 50 um (Condensed Chemical Dictionary, Twelfth Edition).

  4. How do you dispose of Product 452912, Sodium hydride in Mineral Oil?

    In accordance with our MSDS, we recommend you contact a licensed waste disposal company to dispose of this material.  If you have small  quantities to dispose of, the Hazardous Laboratory Chemicals Disposal Guide : 2nd Edition, recommends you wear eye protection, laboratory coat, and nitrile gloves. In the fume hood , mix the hydride with a 1:1:1 mixture by weight of sodium carbonate or calcium carbonate, clay cat litter (bentonite), and sand. Slowly and cautiously add butanol ( about 38 mL/g of hydride) until the reaction ceases. Then add water very carefully until all of the hydride is destroyed. Let stand until solids settle. Decant liquid into the drain. The solid residue may be discarded with normal refuse.

  5. What is the packaging configuration for Product 452912, Sodium hydride in Mineral Oil?

    The 5 gram unit is packaged in an amber glass bottle. The 100 gram and 500 gram quantities are packaged in a paint can. The product is in a bag in the can and the can be opened by removing the plastic seal from the top of the can. An 18 L steel drum is used for packaging the 2 kg and 5 kg size.

  6. When does Product 452912, Sodium hydride in Mineral Oil, decompose?

    According to literature, this product starts to decompose with the evolution of hydrogen at about 255 deg C and completely decomposes at 800 deg C ( Condensed Chemical Dictionary, Twelfth Edition ).

  7. What is Product 452912, Sodium hydride in Mineral Oil, soluble in?

    According to the chemicals encyclopedia published by the Royal Society of Chemistry:13th Edition this product will react explosively with water and violently with lower alcohols.  It is soluble in molten sodium hydroxide and can spontaneously ignite with moist air.

  8. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  9. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  10. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

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