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Merck
CN

450162

Sigma-Aldrich

六氯铱(IV)酸钾

99.99% trace metals basis

别名:

Iridium potassium chloride

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About This Item

线性分子式:
K2IrCl6
CAS号:
分子量:
483.13
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23

质量水平

检测方案

99.99% trace metals basis

形式

powder

杂质

≤150.0 ppm Trace Metal Analysis

mp

>385 °C (lit.)

SMILES字符串

[K+].[K+].Cl[Ir--](Cl)(Cl)(Cl)(Cl)Cl

InChI

1S/6ClH.Ir.2K/h6*1H;;;/q;;;;;;+4;2*+1/p-6

InChI key

WEKZJZDULNNSCD-UHFFFAOYSA-H

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应用

  • Voltammetry at HMT-PMBI-coated glassy carbon electrodes: This study explores the electrochemical properties of potassium hexachloroiridate(IV) and its potential for sensitive detection, which could be valuable in analytical chemistry applications (M Rees et al., 2020).
  • Antioxidant Total Capacity Assay: Introduces a novel assaying method for antioxidant capacity using potassium hexachloroiridate(IV), which could have implications in pharmacology and drug discovery (Y Liu et al., 2024).
  • Mass Transfer in 3D-printed Electrolyzers: Examines the role of potassium hexachloroiridate(IV) in enhancing mass transfer in electrolytic systems, which is pivotal for chemical engineering and energy applications (SJC Weusten et al., 2021).

象形图

Exclamation mark

警示用语:

Warning

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


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Z S Farhangrazi et al.
Biochemistry, 34(46), 14970-14974 (1995-11-21)
Horseradish peroxidase (HRP) was oxidized by IrCl6(2-) to a mixture of compounds I and II, the rate of oxidation and the ratio of the mixture being greatly affected by pH (Hayashi & Yamazaki, 1979). Oxidation of HRP by IrCl6(2-) in
Na Song et al.
Inorganic chemistry, 47(24), 11458-11460 (2008-11-14)
One-electron oxidation of phenol, 2,4,6-trimethylphenol, and 2,6-dimethylphenol by [IrCl(6)](2-) in aqueous solution has a simple pH dependence, indicating slow bimolecular oxidation of ArOH and faster oxidation of ArO(-). H/D kinetic isotope effects as large as 3.5 for oxidation of ArOH
J G Muller et al.
Nucleic acids research, 26(9), 2247-2249 (1998-06-20)
Two gel electrophoretic methods are described for detection of 7, 8-dihydro-8-oxoguanine and 7,8-dihydro-8-oxoadenine based on their further oxidation with one-electron oxidants including IrCl62-and IrBr62-. The products of nucleobase oxidation lead to enhanced piperidine-sensitive cleavage and to highly visible stop points
Y Kaneko et al.
Biochemistry, 19(25), 5795-5799 (1980-12-09)
Zinc-substituted horseradish peroxidase is oxidized by K2IrCl6 to a characteristic state which retains one oxidizing equivalent more than the zinc peroxidase. The oxidized enzyme gives an optical absorption spectrum similar to that of compound I of peroxidase and catalase, and
Fabrizio Testa et al.
Free radical biology & medicine, 51(8), 1567-1574 (2011-08-16)
Unlike superoxide dismutases (SODs), superoxide reductases (SORs) eliminate superoxide anion (O(2)(•-)) not through its dismutation, but via reduction to hydrogen peroxide (H(2)O(2)) in the presence of an electron donor. The microaerobic protist Giardia intestinalis, responsible for a common intestinal disease

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