所有图片(2)
About This Item
线性分子式:
(C6H5)2PH·BH3
CAS号:
分子量:
200.02
MDL编号:
UNSPSC代码:
12352002
PubChem化学物质编号:
NACRES:
NA.22
质量水平
检测方案
98%
形式
solid
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Reductions
reagent type: reductant
bp
148-150 °C/10 mmHg (lit.)
mp
47-50 °C (lit.)
SMILES字符串
B.[H]P(c1ccccc1)c2ccccc2
InChI
1S/C12H11P.BH3/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10,13H;1H3
InChI key
XUFGOLYVDOBYLK-UHFFFAOYSA-N
应用
Reactant for:
- Nucleophilic addition reactions (anion)
- Catalytic dehydrogenation in the presence of ruthenium bidentate phosphine compelxes
- Deprotonation reactions
- Catalytic coupling with alkynyl bromides
- Catalyst-free Staudinger ligation for indirect 18F-radiolabeling
- Preparation of chiral phosphine-phosphite bidentate ligands with biphenyl backbone
- Reactions with frustrated lewis pair combinations of group 14 triflates and sterically hindered nitrogen bases
警示用语：
Danger
危险声明
预防措施声明
危险分类
Water-react 2
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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