所有图片(5)
About This Item
经验公式（希尔记法）:
C6H12ClO2P
CAS号:
分子量:
182.59
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
方案
95%
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
折射率
n20/D 1.471 (lit.)
沸点
81.5-82 °C/13 mmHg (lit.)
密度
1.149 g/mL at 25 °C (lit.)
SMILES字符串
CC1(C)OP(Cl)OC1(C)C
InChI
1S/C6H12ClO2P/c1-5(2)6(3,4)9-10(7)8-5/h1-4H3
InChI key
WGPCXYWWBFBNSS-UHFFFAOYSA-N
应用
2-氯-4,4,5,5-四甲基-1,3,2-二氧磷杂环戊烷(TMDP)可用于：
- 作为试剂用于将醇类和杂原子亲核体类化合物通过亚磷酰化(phosphitylation)反应合成有用的糖基供体和配体。
- 作为亚磷酰化试剂将木质素样品衍生化用于31P NMR分析。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
补充剂危害
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Kraft lignin-based rigid polyurethane foam
Li Y and Ragauskas AJ
J. Wood Chem. Technol., 32(3), 210-224 (2012)
Guo, Y.; Sulikowski, G. A.,
Journal of the American Chemical Society, 120, 1392-1392 (1998)
Synthesis of complex carbohydrates and glycoconjugates: enzyme-based and programmable one-pot strategies.
K M Koeller et al.
Chemical reviews, 100(12), 4465-4494 (2001-12-26)
Characterization of CO2 precipitated Kraft lignin to promote its utilization
Nagy M, et al.
Green Chemistry, 12(1), 31-34 (2010)
Zafer Söyler et al.
ChemSusChem, 10(1), 182-188 (2016-11-23)
The transesterification of maize starch with olive oil or high oleic sunflower oil was studied under homogeneous conditions in the presence of 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD) as catalyst. Most importantly, this method used two renewable resources directly, without any pretreatment or derivatization
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