444014
1,1,1,3,3,3-六氟-2-甲基-2-丙醇
97%
别名:
1,1,1,3,3,3-Hexafluoro-2-hydroxy-2-methylpropane, 1,1,1,3,3,3-Hexafluoro-2-methyl-2-propanol, 1,1,1-Trifluoro-2-trifluoromethyl-2-propanol, 1,1-Bis(trifluoromethyl)ethanol, 2-Methylhexafluoro-2-propanol, Hexafluoro-tert-butanol, Hexafluoro-tert-butyl alcohol
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所有图片(1)
About This Item
线性分子式:
CH3C(CF3)2OH
CAS号:
分子量:
182.06
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
97%
表单
liquid
折射率
n20/D 1.3 (lit.)
沸点
60-62 °C (lit.)
密度
1.484 g/mL at 25 °C (lit.)
官能团
fluoro
hydroxyl
SMILES字符串
CC(O)(C(F)(F)F)C(F)(F)F
InChI
1S/C4H4F6O/c1-2(11,3(5,6)7)4(8,9)10/h11H,1H3
InChI key
FQDXJYBXPOMIBX-UHFFFAOYSA-N
应用
1,1,1,3,3,3-Hexafluoro-2-methyl-2-propanol can be used as a reactant to synthesize:
- Ethyl zinc fluoroalkoxide complexes by using diethyl zinc.
- Vanadium-alkylidene complexes in the presence of hexane.
- 1,1,1,3,3,3-Hexafluoro-2-methyl-2-propylperchlorate using NaH and dichlorine heptoxide in carbon tetrachloride.
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
Chemistry of Materials, 7, 929-929 (1995)
Inorganic Chemistry, 33, 5463-5463 (1994)
Toshiyuki Kida et al.
Chemical communications (Cambridge, England), 50(91), 14245-14248 (2014-10-07)
We found that cyclodextrins (CDs) have a high solubility in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP). Evaporating HFIP from CD solutions on a glass plate gave crystalline solids composed of channel-type CD assemblies, and electrospinning with an HFIP solution of CDs fabricated CD microfibers.
Inorganic Chemistry, 34, 3980-3980 (1995)
Syntheses of Various (Arylimido) vanadium (V)-Dialkyl Complexes Containing Aryloxo and Alkoxo Ligands, and Ring-Opening Metathesis Polymerization Using a Vanadium (V)-Alkylidene Complex
Nomura K, et al.
Organometallics, 27, 3818-3824 (2008)
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