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Merck
CN

442860

Sigma-Aldrich

1-氯-2-辛炔

98%

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About This Item

线性分子式:
CH3(CH2)4C≡CCH2Cl
CAS号:
分子量:
144.64
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

方案

98%

折射率

n20/D 1.46 (lit.)

沸点

40-41 °C/0.5 mmHg (lit.)

密度

0.931 g/mL at 25 °C (lit.)

SMILES字符串

CCCCCC#CCCl

InChI

1S/C8H13Cl/c1-2-3-4-5-6-7-8-9/h2-5,8H2,1H3

InChI key

OUMUOQQKEAGFCJ-UHFFFAOYSA-N

一般描述

1-Chloro-2-octyne is a propargyl halide. Organo-titanium reagent mediated coupling of 1-chloro-2-octyne has been described.

应用

1-Chloro-2-octyne may be used for the synthesis of 1,5-diynes, via reaction with 1,3-dilithiopropyne.

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

154.4 °F - closed cup

闪点(°C)

68 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Qing-Han Li et al.
Organic & biomolecular chemistry, 12(38), 7634-7642 (2014-08-22)
A simple and mild catalytic coupling reaction of propargyl halides with organotitanium reagents is reported. The reaction of propargyl bromide with organo-titanium reagents mediated by NiCl2 (2 mol%) and PCy3 (4 mol%) in CH2Cl2 afforded coupling product allenes in good
Albán R Pereira et al.
The Journal of organic chemistry, 70(7), 2594-2597 (2005-03-25)
[reaction: see text] A new method for the synthesis of 1,5-diynes, from the reaction of 1,3-dilithiopropyne and propargyl chlorides, was developed. This new methodology was used to prepare (4E,6Z,10Z)-4,6,10-hexadecatrien-1-ol, one of the pheromone components of the cocoa pod borer moth
The Dielectric Properties of Acetylenic Compounds. V. Acetylenic Halides and Alcohols.
Toussaint JA and Wenzke HH.
Journal of the American Chemical Society, 57(4), 668-670 (1935)
Palladium-Catalyzed Regioselective Coupling of Propargylic Substrates with Terminal Alkynes. Application to the Synthesis of 1, 2-Dien-4-ynes.
Condon-Gueugnot S and Linstrumelle G.
Tetrahedron, 56(13), 1851-1857 (2000)
Ana Belén Ruiz-Muelle et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 22(7), 2427-2439 (2016-01-21)
The synthesis and structural characterization of allenyl titanocene(IV) [TiClCp2 (CH=C=CH2 )] 3 and propargyl titanocene(IV) [TiClCp2 (CH2 -C≡C-(CH2 )4 CH3 )] 9 have been described for the first time. Advanced NMR methods including diffusion NMR methods (diffusion pulsed field gradient

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