所有图片(1)
About This Item
线性分子式:
(CF3SO3)3In
CAS号:
分子量:
562.03
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
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表单
solid
质量水平
反应适用性
core: indium
reagent type: catalyst
SMILES字符串
[In+3].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
InChI
1S/3CHF3O3S.In/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3
InChI key
UCYRAEIHXSVXPV-UHFFFAOYSA-K
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应用
参与的反应物或试剂：
通过环缩合反应合成苯并恶唑的催化剂
- 稳定的细菌氯化铟的合成
- 磷酰化物对三氟乙酸的碱性研究
- 分子内杂 Diels-Alder 反应制备十氢喹啉类毒素
通过环缩合反应合成苯并恶唑的催化剂
试剂在有机合成中使用路易斯酸催化剂，在催化中作为助催化剂。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Guillaume Compain et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 18(6), 683-691 (2017-01-18)
Metal triflates, often called Lewis superacids, are potent catalysts for organic synthesis. However, the reactivity of a given Lewis superacid toward a given base is difficult to anticipate. A systematic screening of catalysts is often necessary when developing synthetic methodologies.
Yadav, J. S.; Reddy, B. V. S. et al.
Tetrahedron Letters, 43, 1565-1565 (2002)
Frost, C. G.; Chauhan, K. K. et al.
Synlett, 1743-1743 (1999)
Teruhisa Tsuchimoto et al.
Chemical communications (Cambridge, England), (7), 852-853 (2003-05-13)
A palladium-indium triflate catalyst was found to be much more active for the dimerization of vinylarenes compared with generally used cationic palladium(II) catalysts.
Trost, B. M.; Portnoy, M.; Kurihara, H.
Journal of the American Chemical Society, 118, 836-836 (1997)
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