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质量水平
检测方案
97%
形式
solid
mp
157-163 °C (lit.)
SMILES字符串
CCCC[N+](CCCC)(CCCC)CCCC.F[Si-](F)(c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C18H15F2Si.C16H36N/c19-21(20,16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4/h1-15H;5-16H2,1-4H3/q-1;+1
InChI key
RQBKGJOQACIQDG-UHFFFAOYSA-N
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一般描述
四丁基二氟三苯基硅酸铵（TBAT）是一种非吸湿性、可溶性有机氟化物，它是有效的亲核置换反应试剂。此外，TBAT可用作催化促进剂。
应用
亲核氟化反应中的氟源。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
补充剂危害
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Journal of the American Chemical Society, 117, 5166-5166 (1995)
Yansheng Wang et al.
Oncology reports, 38(3), 1579-1586 (2017-07-18)
The aim of this study was to elucidate the effects of iodine-131 on the induction of apoptosis in human cardiac muscle cells and the underlying molecular mechanisms. We found that iodine-131 reduced cell proliferation, induced apoptosis, induced p53, PIDD, t-BID
Tetrabutylammonium Difluorotriphenylsilicate (TBAT )
Simpkins NS, et al.
Encyclopedia of Reagents for Organic Synthesis, Second Edition, 1-14 (2001)
Kohei Fuchibe et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(12), 2831-2838 (2016-12-03)
Silyl dienol ethers, prepared from α,β-unsaturated ketones, underwent proton sponge-catalyzed difluorocyclopropanation with trimethylsilyl 2,2-difluoro-2-fluorosulfonylacetate in a regioselective manner, leading to 1,1-difluoro-2-siloxy-2-vinylcyclopropanes in good yields. The cyclopropanes thus obtained were in turn subjected to fluoride-ion-catalyzed ring opening to afford 1-fluorovinyl vinyl
Nucleophilic addition of TMSCCl3 to N-phosphinoyl benzaldimines: a route to N-phosphinoyl-?-(trichloromethyl)benzylamines
Wahl B, et al.
Tetrahedron Letters, 55(42), 5829-5831 (2014)
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