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同位素纯度
≥99.8 atom % D
质量水平
方案
≥99% (CP)
表单
liquid
expl. lim.
5.5-36.5 % (lit.)
技术
NMR: suitable
杂质
≤0.025% water
折射率
n20/D 1.326 (lit.)
沸点
65.4 °C (lit.)
mp
-99 °C (lit.)
密度
0.888 g/mL at 25 °C (lit.)
包装形式
neat
SMILES字符串
[2H]OC([2H])([2H])[2H]
InChI
1S/CH4O/c1-2/h2H,1H3/i1D3,2D
InChI key
OKKJLVBELUTLKV-MZCSYVLQSA-N
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一般描述
氘代甲醇 （CD3OD）是氘代NMR溶剂，可用于NMR研究和分析。据报道，CD3OD的绝对红外吸收强度在8000和350cm-1之间。
应用
氘代甲醇 可用作溶剂以分析樟脑和降樟脑二甲缩酮中甲氧基的交换速率。
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警示用语：
Danger
危险分类
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1
靶器官
Eyes,Central nervous system
储存分类代码
3 - Flammable liquids
WGK
WGK 2
闪点(°F)
51.8 °F - closed cup
闪点(°C)
11 °C - closed cup
法规信息
危险化学品
美国出口管控1C298产品
Victor V Volkov et al.
The journal of physical chemistry. A, 122(22), 4997-5003 (2018-05-09)
Structural properties of bioinorganic composites are of current interest in the areas of drug delivery, bone repair, and biomimetics. In such composite systems, structural analysis is enhanced when we combine methods of spectroscopy and simulation. Depending on size and shape
Infrared intensities of liquids. XVII. Infrared refractive indices from 8000 to 350 cm-1, absolute integrated absorption intensities, transition moments, and dipole moment derivatives of methan-d3-ol and methanol-d4 at 25?C.
Bertie JE and Zhang SL.
J. Chem. Phys. , 101(10), 8364-8379 (1994)
The Rates of Methoxyl Exchange of Camphor and Norcamphor Dimethyl Ketals in Methanol-d4.
Traylor TG and Perrin CL.
Journal of the American Chemical Society, 88(21), 4934-4942 (1966)
Cheng-Kun Lin et al.
Organic & biomolecular chemistry, 13(7), 2100-2107 (2014-12-20)
A straightforward synthesis of novel, 2-heterocyclyl polyhydroxylated pyrrolidines is described. Stereocontrolled additions of nucleophiles to cyclic nitrones generated the corresponding 2,3-trans adducts, allowing the synthesis of the corresponding pyrrolidines via key intermediates bearing an alkyne and a nitrile oxide. Three
Jon Kapla et al.
Physical chemistry chemical physics : PCCP, 17(34), 22438-22447 (2015-08-08)
The disaccharide trehalose (TRH) strongly affects the physical properties of lipid bilayers. We investigate interactions between lipid membranes formed by 1,2-dimyristoyl-sn-glycero-3-phosphocholine (DMPC) and TRH using NMR spectroscopy and molecular dynamics (MD) computer simulations. We compare dipolar couplings derived from DMPC/TRH
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