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Merck
CN

441244

Sigma-Aldrich

多聚甲醛

prilled, 95%

别名:

聚氧亚甲基

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About This Item

线性分子式:
HO(CH2O)nH
CAS号:
分子量:
30.03 (as monomer)
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

1.03 (vs air)

质量水平

蒸汽压

<1.45 mmHg ( 25 °C)

检测方案

95%

形式

prilled

自燃温度

572 °F

expl. lim.

73 %

mp

120-170 °C (lit.)

转变温度

sublimation point 150 °C

溶解性

alcohol and cold water: slightly soluble
ethers, hydrocarbons and carbon tetrachloride: insoluble

密度

0.88 g/mL at 25 °C (lit.)

InChI

1S/CH2O/c1-2/h1H2

InChI key

WSFSSNUMVMOOMR-UHFFFAOYSA-N

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一般描述

多聚甲醛是甲醛的聚合产物,用于合成热固性聚合物的聚酯反应。

多聚甲醛也称聚甲醛。它在钌催化剂存在下可参与二烯、炔烃和丙二烯的区域选择性还原偶联反应。它还通过烯烃的烷氧基羰基化反应参与酯的合成。

应用

多聚甲醛可用于制备偶氮甲碱叶立德、α-亚甲基色烷、α-亚甲基喹啉和醌甲基化物。
甲醛可制备苯酚-、脲-、糠醇-、间苯二酚-和三聚氰胺-甲醛聚合物,用于涂料、木制品、纺织品和铸造用树脂。

特点和优势

提供无甲醇的甲醛。
在热水中降解成甲醛。

警示用语:

Danger

危险分类

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Flam. Sol. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品

分析证书(COA)

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. How do I find price and availability?

    There are several ways to find pricing and availability for our products. Once you log onto our website, you will find the price and availability displayed on the product detail page. You can contact any of our Customer Sales and Service offices to receive a quote.  USA customers:  1-800-325-3010 or view local office numbers.

  4. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  5. What are the differences between the Paraformaldheyde products and which is best suited for use as a fixative for Electron Microscopy?

    Product 16005 is sold only in Europe and is not available to US customers.The primary differences among the various products is in the form for each product.  P6148 is listed as crystalline, 158127 is listed as powder, and 441244 is listed as prilled. The product information page for 441244 states the prilled form will go into solution more readily, but the prilled, crystalline, and powder forms are equivalent in terms on use. The prilled form is expected to slow down the rate of sublimation compared to the powder or the crystalline forms.  Any of the 3 products should be suitable for use as a fixative.  However, once prepared, paraformaldehyde solutions are unstable unless methanol is added as a stabilizer. Customer options vary from preparing solutions daily to storing solutions for 2 or 3 weeks. If used as a fixative for electron microscopy, we recommend preparing solutions fresh daily to avoid the risk of repeating tedious EM work due to deterioration of the fixative.  For less critical applications, it would be more acceptable to use solutions stored for longer periods of time.

  6. My question is not addressed here, how can I contact Technical Service for assistance?

    Ask a Scientist here.

Brannon Sam et al.
Angewandte Chemie (International ed. in English), 54(11), 3267-3274 (2014-11-29)
Ruthenium-catalyzed reductive couplings of paraformaldehyde with dienes, alkynes, and allenes provide access to products of hydrohydroxymethylation that cannot be formed selectively under the conditions of hydroformylation. In certain cases, the regioselectivity of the CC coupling can be inverted by using
J Justin Mulvey et al.
International journal of nanomedicine, 9, 4245-4255 (2014-09-18)
We aimed to create a more robust and more accessible standard for amine-modifying single-walled carbon nanotubes (SWCNTs). A 1,3-cycloaddition was developed using an azomethine ylide, generated by reacting paraformaldehyde and a side-chain-Boc (tert-Butyloxycarbonyl)-protected, lysine-derived alpha-amino acid, H-Lys(Boc)-OH, with purified SWCNT
Ruthenium-Catalyzed Alkoxycarbonylation of Alkenes with Paraformaldehyde as a Carbon Monoxide Substitute.
Liu Q, et al.
ChemCatChem, 6(10), 2805-2809 (2014)
Synthesis of ethanol from paraformaldehyde, CO 2 and H 2
Green Chemistry, 19, 4396-4401 (2017)
Aditi Dubey et al.
PloS one, 11(11), e0165642-e0165642 (2016-11-02)
Selenocysteine (Sec) is a critical residue in at least 25 human proteins that are essential for antioxidant defense and redox signaling in cells. Sec is inserted into proteins cotranslationally by the recoding of an in-frame UGA termination codon to a

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