推荐产品
方案
98%
旋光性
[α]20/D −19.5°, c = 2 in DMF
mp
98-102 °C (lit.)
SMILES字符串
[H][C@@](CC(=O)OCc1ccccc1)(NC(=O)OC(C)(C)C)C(O)=O
InChI
1S/C16H21NO6/c1-16(2,3)23-15(21)17-12(14(19)20)9-13(18)22-10-11-7-5-4-6-8-11/h4-8,12H,9-10H2,1-3H3,(H,17,21)(H,19,20)/t12-/m0/s1
InChI key
SOHLZANWVLCPHK-LBPRGKRZSA-N
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应用
用于光学异构合成 (R)-(+)-Boc-iturinic acid (n-C14)、L-天冬氨酸系列凝血酶抑制剂，以及二酮哌嗪四肽的原料。用于制备位于 [6H]-氮杂卓并吲哚啉中心的新型模拟三环二肽。
储存分类代码
13 - Non Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
Bergeron, R.J. et al.
Journal of the American Chemical Society, 116, 8479-8479 (1994)
K Hilpert et al.
Journal of medicinal chemistry, 37(23), 3889-3901 (1994-11-11)
Thrombin, a serine protease, plays a central role in the initiation and propagation of thrombotic events. An extensive search for new thrombin inhibitors was performed, using an unconventional approach. Screening of small basic molecules for binding in the recognition pocket
Bland, J.M.
Synthetic Communications, 25, 467-467 (1995)
De Lombaert, S. et al.
Tetrahedron Letters, 35, 7513-7513 (1994)
Nicole Niklas et al.
Dalton transactions (Cambridge, England : 2003), (1)(1), 154-162 (2006-12-13)
The amino acid derivative Boc-Asp-OBzl (Boc=N-butyloxycarbonyl; Asp=aspartic acid; Bzl=benzyl) was functionalized by coupling its carboxylate side chain to dipicolylamine. This yielded the tridentate nitrogen donor ligand Boc-Asp(Dpa)-OBzl (-OBzl). The compound -OBzl contains three different carbonyl groups: a tertiary amide linkage
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