440272
二氯二甲基硅烷
≥99.5%
别名:
DMDCS, 二甲基二氯硅烷
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关于此项目
线性分子式:
(CH3)2SiCl2
化学文摘社编号:
分子量:
129.06
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-901-0
Beilstein/REAXYS Number:
605287
MDL number:
产品名称
二氯二甲基硅烷, ≥99.5%
InChI key
LIKFHECYJZWXFJ-UHFFFAOYSA-N
InChI
1S/C2H6Cl2Si/c1-5(2,3)4/h1-2H3
SMILES string
C[Si](C)(Cl)Cl
assay
≥99.5%
form
liquid
refractive index
n20/D 1.404 (lit.)
bp
70 °C (lit.)
mp
−76 °C (lit.)
density
1.07 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
用于与叔醇反应制备树脂键合硅氧烷。
用于合成光学活性柄型金属茂聚合催化剂的常用试剂。
Packaging
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
33.8 °F - closed cup
flash_point_c
1 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Tetrahedron, 63, 299-299 (2007)
Cliff R Baar et al.
Journal of the American Chemical Society, 126(26), 8216-8231 (2004-07-01)
A series of enantiopure C1-symmetric metallocenes, [(SiMe2)2[eta5-C5H(CHMe2)2][eta5-C5H2((S)-CHMeCMe3)]]ZrCl2, (S)-2, [(SiMe2)2[eta5-C5H(CHEt2)2][eta5-C5H2((S)-CHMeCMe3)]]ZrCl2, (S)-6, and [(SiMe2)2[eta5-C5HCy2][eta5-C5H2((S)-CHMeCMe3)]]ZrCl2, (S)-7 (Cy = cyclohexyl), zirconocene dichlorides that have an enantiopure methylneopentyl substituent on the "upper" cyclopentadienyl ligand, and diastereomerically pure precatalysts, [(SiMe2)2[eta5-C5H((S)-CHMeCy)(CHMe2)][eta5-C5H3]]ZrCl2, (S)-8a and (S)-8b, which have an
Y C Tseng et al.
Biomaterials, 16(13), 963-972 (1995-09-01)
Amphipathic ethylene glycol-butadiene block copolymers (PEG-PB) with different chain lengths of poly(ethylene glycol) (PEG) were synthesized by reacting poly(ethylene glycol methyl ether) (m-PEG, mol. wt = 350, 550, 750, 2000 and 5000) with telechelic polybutadiene (PB). The PEG-PB copolymers formed
Zhanhui Wang et al.
Journal of biochemical and biophysical methods, 57(3), 203-211 (2003-09-27)
The feasibility of using protein A to immobilize antibody on silicon surface for a biosensor with imaging ellipsometry was presented in this study. The amount of human IgG bound with anti-IgG immobilized by the protein A on silicon surface was
Takehiro Fukuzaki et al.
Organic letters, 4(17), 2877-2880 (2002-08-17)
[reaction: see text] Studies on the connection between the right and left segments of azadirachtin are described. The Ireland-Claisen rearrangement of Li-enolate of the modeled ester with dichlorodimethylsilane in toluene afforded the desired limonoid framework stereoselectively in good yield.
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