所有图片(1)
About This Item
线性分子式:
NaN3
CAS号:
分子量:
65.01
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
方案:
≥99.99% trace metals basis
表单:
solid
溶解性:
soluble 65 g/L at 20 °C (completely)
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方案
≥99.99% trace metals basis
表单
solid
反应适用性
reaction type: click chemistry
溶解性
soluble 65 g/L at 20 °C (completely)
SMILES字符串
[Na]N=[N+]=[N-]
InChI
1S/N3.Na/c1-3-2;/q-1;+1
InChI key
PXIPVTKHYLBLMZ-UHFFFAOYSA-N
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应用
Efficient 1,4-addition of azide to a,ß-unsaturated aldehydes in the presence of tertiary amines.
Catalyst for:
Reagent for synthesis of
Involved in regioselective synthesis of prianosin B
Catalyst for:
- Oxidative decarboxylation
- Michael addition reactions
Reagent for synthesis of
- Blue fluorescent copolymers
- Metal phosphonates
- Arenes via aminations
Involved in regioselective synthesis of prianosin B
警示用语：
Danger
危险分类
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2 Oral
靶器官
Brain
补充剂危害
储存分类代码
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
法规信息
新产品
Synthetic Communications, 37, 1027-1027 (2007)
Y. Wada, et al.,
Tetrahedron, 65, 1059-1062 (2009)
H. Chen, et al.,
Macromolecules, 43, 3613-3623 (2010)
Xiaohua Sun et al.
Organic letters, 9(22), 4495-4498 (2007-10-04)
A novel intermolecular cross-double-Michael addition between nitro and carbonyl activated olefins has been developed through Lewis base catalysis. The reaction took place with a large group of beta-alkyl nitroalkenes and alpha,beta-unsaturated ketone/esters, producing an allylic nitro compound in good to
V. N. Telvekar and K. A. Sasane,
Synlett, 18, 2778-2780 (2010)
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