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![聚[N,N′-(1,3-亚苯基)间苯二酰胺]](/deepweb/assets/sigmaaldrich/product/structures/395/463/bcad501a-7c15-4fcc-a469-b743bb78bb3b/640/bcad501a-7c15-4fcc-a469-b743bb78bb3b.png)
质量水平
检测方案
97%
形式
liquid
折射率
n20/D 1.519 (lit.)
bp
95-96 °C/11 mmHg (lit.)
密度
0.91 g/mL at 25 °C (lit.)
SMILES字符串
CC(C)N(C(C)C)c1ccccc1
InChI
1S/C12H19N/c1-10(2)13(11(3)4)12-8-6-5-7-9-12/h5-11H,1-4H3
InChI key
OVSARSKQWCLSJT-UHFFFAOYSA-N
一般描述
N,N-Diisopropylaniline is an N,N-dialkylaniline. Its borane adducts have been prepared and reported as hydroborating agents. Thermal dissociation of the borane-N,N-diisopropylaniline adduct has been reported to afford gaseous diborane. N,N-Diisopropylaniline is a diisoproplyamino derivative that can be prepared by reacting bromobenzene with diisopropylamine.
应用
N,N-Diisopropylaniline was used for the synthesis of 4-diisopropylamino benzonitrile. It may be used for the synthesis of 6-(4-bromophenyl)-3-methoxy-5-methyl-8-oxabicyclo[3.2.1]octa-3,6-dien-2-one and N,N,N′,N′-tetraisopropylbenzidine.
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
183.2 °F
闪点(°C)
84 °C
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Yvonne D Williams et al.
The Journal of organic chemistry, 78(23), 11707-11713 (2013-11-01)
Methoxytropolones are useful scaffolds for therapeutic development because of their known biological activity and established value in the synthesis of α-hydroxytropolones. Upon treatment with triflic acid, a series of 3-methoxy-8-oxabicyclo[3.2.1]octa-3,6-dien-2-ones rearrange rapidly and cleanly to form methoxytropolones. Interestingly, bicycles that
Synthesis of N,N,N',N'-tetraalkylbenzidines through oxidative coupling of N,N-dialkylarylamines induced by SbCl5.
Vitale P, et al.
ARKIVOC (Gainesville, FL, United States), 3, 36-48 (2013)
N-alkylation of hindered secondary aromatic amines with 2-iodobutane.
Katritzky AR, et al.
ORL; Journal for Oto-Rhino-Laryngology and Its Related Specialties, 23(4), 399-402 (1991)
Dual fluorescence and fast intramolecular charge transfer with 4-(diisopropylamino) benzonitrile in alkane solvents.
Demeter A, et al.
Chemical Physics Letters, 323(3), 351-360 (2000)
Brown et al.
The Journal of organic chemistry, 65(15), 4655-4661 (2000-08-26)
Several N,N-diethyl-tert-alkylamines, such as N,N-diethyl-2-methyl-2-butylamine (1, t-PentNEt2), N,N-diethyl-2,3-dimethyl-2-butylamine (2, t-HexNEt2), N,N-diethyl-2,3,3-trimethyl-2-butylamine (3, t-HeptNEt2), and N,N-diethyl-1,1,3,3-tetramethylbutylamine (4, t-OctNEt2) with varying steric bulk around nitrogen (by changing the tert-alkyl group) have been prepared and examined as borane carriers. The complexing ability of
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