436267
二碳酸二叔丁酯 溶液
1.0 M in THF
别名:
焦碳酸二叔丁酯
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关于此项目
线性分子式:
O[CO2C(CH3)3]2
化学文摘社编号:
分子量:
218.25
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
InChI
1S/C10H18O5/c1-9(2,3)14-7(11)13-8(12)15-10(4,5)6/h1-6H3
SMILES string
CC(C)(C)OC(=O)OC(=O)OC(C)(C)C
InChI key
DYHSDKLCOJIUFX-UHFFFAOYSA-N
form
liquid
concentration
1.0 M in THF
bp
65-67 °C
density
0.913 g/mL at 25 °C
application(s)
peptide synthesis
functional group
carbonate
Quality Level
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signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Hans Peter Reisenauer et al.
Angewandte Chemie (International ed. in English), 53(44), 11766-11771 (2014-09-10)
Carbonic acid (H2CO3), an essential molecule of life (e.g., as bicarbonate buffer), has been well characterized in solution and in the solid state, but for a long time, it has eluded its spectral characterization in the gas phase owing to
Jason C Green et al.
Organic letters, 13(20), 5500-5503 (2011-09-21)
Total syntheses of two structures purported as (+)-heliananes were completed in six pots. Spectral comparisons, between the synthetic and natural compounds, revealed a misassignment of the eight-membered ring in the heliananes. The key step in the syntheses of the proposed
Giuseppe Bartoli et al.
The Journal of organic chemistry, 71(26), 9580-9588 (2006-12-16)
The reaction between alcohols and Boc2O leads to the formation of tert-butyl ethers and/or Boc-alcohols, depending on the nature of the Lewis acid catalyst. Product distribution is mainly tuned by the anionic part of the salt. Perchlorates and triflates, anions
J S Allen et al.
Mutation research, 170(1-2), 23-29 (1986-04-01)
The Ames Salmonella/mammalian-microsome assay was used to evaluate the bacterial mutagenicity of 6 bioactive peptides and of 11 chemical reagents used in peptide synthesis. Samples of 2 reagents, bis(2-oxo-3-oxazolidinyl)phosphinic chloride and fluoren-9-ylmethyl chloroformate, showed mutagenic activity with strains TA100 and
Diana Vivian et al.
International journal of pharmaceutics, 475(1-2), 597-604 (2014-09-16)
Floxuridine is often used to treat metastatic liver disease and is given as an infusion directly into the hepatic artery to increase the amount of intact drug that reaches the liver. The objective of this work was to design and
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