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蒸汽密度
2 (vs air)
质量水平
蒸汽压
14.39 psi ( 55 °C)
184 mmHg ( 20 °C)
3.67 psi ( 20 °C)
同位素纯度
99.9 atom % D
方案
≥99% (CP)
表单
liquid
包含
0.03 % (v/v) TMS
expl. lim.
13.2 %
包装
ampule of 1 mL, 10 g
glass bottle of 10 g, 25 g, 50 g
技术
NMR: suitable
杂质
≤0.0500% water
water
折射率
n20/D 1.355 (lit.)
沸点
55.5 °C (lit.)
mp
−93.8 °C (lit.)
密度
0.872 g/mL at 25 °C (lit.)
质量偏移
M+6
SMILES字符串
[2H]C([2H])([2H])C(=O)C([2H])([2H])[2H]
InChI
1S/C3H6O/c1-3(2)4/h1-2H3/i1D3,2D3
InChI key
CSCPPACGZOOCGX-WFGJKAKNSA-N
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一般描述
丙酮-d6 是一种含有 0.03%(v/v)TMS(四甲基硅烷)的氘代 NMR 溶剂。它可用于在基于 NMR 的研究和分析。已经对其红外光谱和拉曼光谱进行了分析。已经研究了丙酮-d6 和甲烷混合物的热解和光解随温度的变化。据报道,它是通过在汞催化剂存在下由重水与丙炔-d4 反应制得的。
应用
丙酮-d 6 可能作为内标物,采用顶空固相微萃取和气相色谱-质谱法检测水中的醛和丙酮。
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警示用语:
Danger
危险声明
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
靶器官
Central nervous system
补充剂危害
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
-2.2 °F - closed cup
闪点(°C)
-19 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves
法规信息
危险化学品
美国出口管控1C298产品
Vibrational spectra and assignment of acetone, ααα acetone-d3 and acetone-d6.
Spectrochimica Acta Part A: Molecular Spectroscopy, 22(4), 593-614 (1966)
Journal of separation science, 34(6), 693-699 (2011-02-15)
We describe a simple and automatic method to determine nine aldehydes and acetone simultaneously in water. This method is based on derivatization with 2,2,2-trifluoroethylhydrazine (TFEH) and consecutive headspace-solid-phase microextraction and gas chromatography-mass spectrometry. Acetone-d(6) was used as the internal standard.
The Pyrolysis and Photolysis of Acetone-d6 in the Presence of Methane.
Journal of the American Chemical Society, 76(16), 4196-4198 (1954)
Neue Synthese von Aceton-d6.
Helvetica Chimica Acta, 45(1), 59-62 (1962)
Dalton transactions (Cambridge, England : 2003), 44(8), 3604-3613 (2014-11-20)
Linear and circular dichroism (LD and CD) spectroscopy as well as isothermal titration calorimetry (ITC) have been used to investigate the interaction of Ru(tpy)(py)dppz(2+) (tpy = 2,2':6',2''-terpyridyl; py = pyridine; dppz = dipyrido[3,2-a:2'3'-c]phenazine) with DNA, providing detailed information about the
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