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About This Item
经验公式（希尔记法）:
C5H3BrO2
CAS号:
分子量:
174.98
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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应用
5-Bromo-2-furaldehyde may be employed for the following syntheses:
- 5-substituted 2-furaldehydes
- anilines, through a novel one-pot, two-step amination/Diels-Alder procedure
- 5-(5′,8′-dimethyl-9′-tert-butoxycarbonyl-9′H-carbazol-3′-yl)-furan-2-carbaldehyde
- 5-(6-hydroxyhexyl)-2-furaldehyde
- 5-methylsulfonyl-2-furaldehyde
- 5-phenylsulfonyl-2-furaldehyde
- 5-(4-acetamidobenzylsulfonyl)-2-furaldehyde
- 5-iodo-2-furaldehyde
警示用语：
Warning
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
法规信息
新产品
Furan derivatives. LXXXV11. The synthesis and ultraviolet spectra of 5-(4-X-phenyIsulfonyI)-2-furaldehydes and 2-cyano-3-[5-(4-X-phenyl-sulfonyl)-2-furyl] acrylonitriles.
Kada R and Kovac J.
Chemical Papers, 30(4), 502-507 (1976)
Efficient and Simple Synthesis of 6-Aryl-1,4-dimethyl-9H-carbazoles.
Caruso A, et al.
Molecules (Basel), 13(6), 1312-1320 (2008)
A synthesis strategy yielding skeletally diverse small molecules combinatorially.
Burke MD, et al.
Journal of the American Chemical Society, 126(43), 14095-14104 (2004)
Raouf Medimagh et al.
The Journal of organic chemistry, 73(6), 2191-2197 (2008-02-28)
Selective metal-free amination and Diels-Alder reactions are described in the furan series, leading to polysubstituted anilines or to stable oxabicyclic adducts in high yield. Interestingly, anilines are conveniently prepared through a novel one-pot, two-step amination/Diels-Alder procedure from commercially available 5-bromo-2-furaldehyde.
Aminomethylations via cross-coupling of potassium organotrifluoroborates with aryl bromides.
Molander GA and Sandrock DL.
Organic Letters, 9(8), 1597-1600 (2007)
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