所有图片(1)
About This Item
线性分子式:
C6H5CH(CH3)NHCH2C6H5
CAS号:
分子量:
211.30
Beilstein:
3589990
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
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方案
98%
旋光性
[α]20/D +38°, neat
光学纯度
ee: ≥97% (HPLC)
折射率
n20/D 1.564 (lit.)
沸点
171 °C/15 mmHg (lit.)
密度
1.01 g/mL at 25 °C (lit.)
官能团
amine
phenyl
SMILES字符串
C[C@@H](NCc1ccccc1)c2ccccc2
InChI
1S/C15H17N/c1-13(15-10-6-3-7-11-15)16-12-14-8-4-2-5-9-14/h2-11,13,16H,12H2,1H3/t13-/m1/s1
InChI key
ZYZHMSJNPCYUTB-CYBMUJFWSA-N
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应用
用于对映选择性脱质子化反应的手性胺。
(R)-(+)-N-Benzyl-α-methylbenzylamine may be used to prepare:
- tert-Butyl (3S)-3-{benzyl[(1R)-1-phenylethyl]amino}-3-(6-methoxypyridin-3-yl)propanoate, an intermediate for the synthesis of the Merck & Co. Inc., Kenilworth, NJ, U.S. αvβ3 integrin antagonist.
- A conformationally restricted piperidine-based analog of deoxynegamycin.
- 5- and 6-[2,3]-dihydrobenzofuran β-amino acids, which can act as aspartic acid mimetics.
警示用语：
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Conformationally restricted analogs of deoxynegamycin.
Raju B, et al.
Bioorganic & Medicinal Chemistry Letters, 14(12), 3103-3107 (2004)
Syntheses of 5-and 6-[2,3]-dihydrobenzofuran ?-amino acids.
Coleman PJ, et al.
Tetrahedron Letters, 41(31), 5803-5806 (2000)
An Efficient Synthesis of an av?3 Antagonist.
Yasuda N, et al.
The Journal of Organic Chemistry, 69(6), 1959-1966 (2004)
Price, D. Simpkins, N.S.
Tetrahedron Letters, 36, 6135-6135 (1995)
Bunn, B.J. Simpkins, N.S.
The Journal of Organic Chemistry, 58, 533-533 (1993)
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