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质量水平
方案
≥98.0% (T)
mp
193-195 °C (lit.)
193-196 °C
溶解性
0.1 M NaOH: soluble 0.5 g/10 mL, clear, colorless
SMILES字符串
OP(=O)(c1ccccc1)c2ccccc2
InChI
1S/C12H11O2P/c13-15(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H,(H,13,14)
InChI key
BEQVQKJCLJBTKZ-UHFFFAOYSA-N
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一般描述
二苯基膦酸 (DPPA，hdpp) 是一种有机膦酸化合物。它在钯催化体系中用作反应性阻燃剂和促进剂。采用热重分析 (TGA) 法研究了二苯甲酮 (DPPA) 的热降解。在二甲基甲酰胺溶剂中，DPPA 与硝酸镉反应生成一维配位聚合物链聚 [[双（二甲基甲酰胺-κO）镉 (II)]-双（μ-二苯基膦酸-κ (2)O:O′）]。已有促进硝基苯和苯胺羰基化合成二苯基脲的方法的报告。 邻位 锂化 DPPA 可通过亲电捕获和联苯-2,2′ 形成单 邻位 功能化衍生物-铜催化偶联苯基膦酸。
应用
二苯基膦酸是合成有机膦化合物的重要起始原料。二苯基次膦酸可在二甲基甲酰胺 (DMF) 溶剂中通过与碱土金属盐反应制备配位聚合物 ：
- [Mg3(O2PPh2)6(DMF)2]·2DMF
- [Ca (O 2 PPh 2 ) 2 (DMF) 2 ]
- [Sr (O 2 PPh 2 ) 2 (DMF) 2 ]
- [Ba(O2PPh2)2(DMF)2]
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
A novel diphenylphosphinic acid coadsorbent for dye-sensitized solar cell.
Shen H, et al.
Electrochimica Acta, 56(5), 2092-2097 (2011)
Jeffrey A Rood et al.
Acta crystallographica. Section C, Structural chemistry, 70(Pt 11), 1069-1074 (2014-11-06)
Reaction of cadmium nitrate with diphenylphosphinic acid in dimethylformamide solvent yielded the one-dimensional coordination polymer catena-poly[[bis(dimethylformamide-κO)cadmium(II)]-bis(μ-diphenylphosphinato-κ(2)O:O')], [Cd(C12H10O2P)2(C3H7NO)2]n, (I). Addition of 4,4'-bipyridine to the synthesis afforded a two-dimensional extended structure, poly[[(μ-4,4'-bipyridine-κ(2)N:N')bis(μ-diphenylphosphinato-κ(2)O:O')cadmium(II)] dimethylformamide monosolvate], {[Cd(C12H10O2P)2(C10H8N2)]·C3H7NO}n, (II). In (II), the 4,4'-bipyridine molecules link
Jeffrey A Rood et al.
Acta crystallographica Section B, Structural science, crystal engineering and materials, 70(Pt 3), 602-607 (2014-06-04)
Reaction of alkaline earth metal salts with diphenylphosphinic acid in dimethylformamide solvent afforded four coordination polymers: [Mg3(O2PPh2)6(DMF)2]·2DMF (I), [Ca(O2PPh2)2(DMF)2] (II), [Sr(O2PPh2)2(DMF)2] (III) and [Ba(O2PPh2)2(DMF)2] (IV) (where DMF is N,N-dimethylformamide). Single-crystal X-ray diffraction revealed that all four compounds produce linear chain
Thermal kinetics and decomposition mechanism of methylphenylphosphinic acid and diphenylphosphinic acid.
Shao X, et al.
Chemical Research in Chinese Universities, 30(6), 1028-1031 (2014)
The palladium-phenanthroline catalyzed carbonylation of nitroarenes to diarylureas: Effect of chloride and diphenylphosphinic acid.
Gasperini M, et al.
Journal of Organometallic Chemistry, 690(20), 4517-4529 (2005)
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