431508
氯化锡(II) 二水合物
ACS reagent grade, ≥99.99% trace metals basis
别名:
氯化亚锡 二水合物
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关于此项目
线性分子式:
SnCl2 · 2H2O
化学文摘社编号:
分子量:
225.65
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
231-868-0
MDL number:
产品名称
氯化锡(II) 二水合物, ≥99.99% trace metals basis
InChI key
FWPIDFUJEMBDLS-UHFFFAOYSA-L
InChI
1S/2ClH.2H2O.Sn/h2*1H;2*1H2;/q;;;;+2/p-2
SMILES string
O.O.Cl[SnH2]Cl
grade
ACS reagent
assay
≥99.99% trace metals basis
reaction suitability
core: tin, reagent type: catalyst
Quality Level
bp
652 °C
mp
37-38 °C (dec.) (lit.)
cation traces
Ca: ≤0.005%, Fe: ≤0.003%, K: ≤0.005%, Na: ≤0.01%, Pb: ≤0.01%
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Application
还原剂；羰基烯丙基化反应；路易斯酸催化剂，用于C-C键形成反应；以AgClO4为催化剂，合成α-糖苷；烯烃、二烯、顺式-乙烯基环氧乙烷和烯丙基硒化物的合成；1,4-内过氧化物的脱氧反应；作为1,3-二噻烷，保护羧酸；选择性对甲氧基苄基醚裂解试剂；加氢甲酰化和羰基化反应的添加剂。
Features and Benefits
符合 A.C.S. 试剂规范。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3
target_organs
Cardio-vascular system, Respiratory system
存储类别
8B - Non-combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
David J Hallett et al.
Organic & biomolecular chemistry, 10(30), 6130-6158 (2012-04-20)
Reactions of the allyltin trichloride 45 generated from (4S)-4-benzyloxypent-2-enyl(tributyl)stannane 1 with imines prepared from glyoxylates proceed with useful levels of 1,5-stereocontrol in favour of (4E)-2,6-anti-2-(alkylamino)-6-benzyloxyhept-4-enoates 49. This stereoselectivity, controlled by the chirality of the stannane, dominates over any intrinsic stereochemical
Grégory Dupeyre et al.
Organic & biomolecular chemistry, 9(22), 7780-7790 (2011-10-07)
A six-step one-pot reaction was designed for synthesizing homodimeric 7-phenylindolo[3,2-a]carbazoles from 1H-indoles and β-nitrostyrenes, in the presence of SnCl(2)·2H(2)O. The reactions proceeded under very mild conditions and the desired heterocycles were obtained in moderate to good yields. An unprecedented mechanism
Matthew Currie et al.
Inorganic chemistry, 52(4), 1710-1721 (2012-06-09)
The anionic speciation of chlorostannate(II) ionic liquids, prepared by mixing 1-alkyl-3-methylimidazolium chloride and tin(II) chloride in various molar ratios, χ(SnCl2), was investigated in both solid and liquid states. The room temperature ionic liquids were investigated by (119)Sn NMR spectroscopy, X-ray
Qiu-Sha Tang et al.
International journal of nanomedicine, 6, 3077-3085 (2011-12-14)
The purpose of this study was to develop intraperitoneal hyperthermic therapy based on magnetic fluid hyperthermia, nanoparticle-wrapped cisplatin chemotherapy, and magnetic particles of albumin. In addition, to combine the multiple-killing effects of hyperthermal targeting therapy, chemotherapy, and radiotherapy, the albumin-nanoparticle
Aili Sun et al.
Talanta, 88, 259-264 (2012-01-24)
The Zn-Sn nanoparticles/multiwall carbon nanotubes (Zn-SnNPs/MWNTs) nanocomposite film was prepared by electrodeposition of ZnCl(2) and SnCl(2) on MWNTs simultaneously in Ethaline ionic liquids. Then, based on immobilizing hemoglobin (Hb) within a novel Zn-SnNPs/MWNTs nanocomposite film (Hb/Zn-SnNPs/MWNTs), a novel hydrogen peroxide
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