431338
硝酸铈(IV)铵
99.99%
别名:
硝酸铈铵
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关于此项目
线性分子式:
Ce(NH4)2(NO3)6
化学文摘社编号:
分子量:
548.22
UNSPSC Code:
12352302
PubChem Substance ID:
EC Number:
240-827-6
MDL number:
InChI key
WIBGOERAEYJBOT-UHFFFAOYSA-N
InChI
1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;
SMILES string
N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
assay
99.99%
reaction suitability
reagent type: oxidant
impurities
≤0.05% insol. dil. H2SO4, <100 ppm total metallic impurities
anion traces
chloride (Cl-): ≤0.01%, phosphate (PO43-): ≤0.02%
cation traces
Fe: ≤0.005%
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Application
提供通过温和条件下氧化丙二酸盐得到丙醇二酸衍生物的一种新途径。
Features and Benefits
符合 ACS 试剂规范。
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A
存储类别
5.1B - Oxidizing hazardous materials
wgk
WGK 3
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Nair, V. et al.
Tetrahedron Letters, 39, 2801-2801 (1998)
David Kesselring et al.
Journal of the American Chemical Society, 130(34), 11290-11291 (2008-08-06)
Conditions for a site-selective ceric ammonium nitrate oxidation have been developed. The reactions proceed nicely on both 1K- and 12K-microelectrode arrays. The procedure for developing the reactions was very simple and demonstrated that the same reagents used for a solution-phase
Rasika Tankhiwale et al.
Colloids and surfaces. B, Biointerfaces, 69(2), 164-168 (2009-01-10)
The present work describes ceric ammonium nitrate (CAN) initiated graft copolymerization of acrylamide onto cellulose-based filter paper followed by entrapment of silver nanoparticles. The copolymerization was carried out in aqueous solution, containing 2M acrylamide monomer and 16mM N,N'-methylene bisacrylamide (MB)
Yue Qi Ye et al.
Bioscience, biotechnology, and biochemistry, 74(11), 2342-2344 (2010-11-13)
The structure of a long-known natural pigment, atromentin, was established by a total synthesis based on double Suzuki-Miyaura coupling and by a single-crystal X-ray analysis of the synthetic sample thereby obtained. A similar strategy including ceric ammonium nitrate (CAN) oxidation
S Sudha et al.
Ultrasonics sonochemistry, 19(5), 994-998 (2012-03-09)
Tetrahydrobenzo[c]xanthenes-11-ones was synthesized by a three component reaction of α-naphthol, aromatic aldehyde and dimedone. Ceric ammonium nitrate acts as a suitable eco-friendly catalyst for this method. Shorter reaction duration, mild reaction condition and low cost make this protocol more effective.
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