43088
二苯基碘酰氯
≥98.0% (AT)
别名:
DPI, NSC 134275
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关于此项目
线性分子式:
(C6H5)2I+Cl-
化学文摘社编号:
分子量:
316.57
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-049-8
Beilstein/REAXYS Number:
3574977
MDL number:
Assay:
≥98.0% (AT)
InChI key
RSJLWBUYLGJOBD-UHFFFAOYSA-M
InChI
1S/C12H10I.ClH/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;1H/q+1;/p-1
SMILES string
[Cl-].[I+](c1ccccc1)c2ccccc2
assay
≥98.0% (AT)
reaction suitability
reagent type: oxidant
mp
233-235 °C (subl.) (lit.)
functional group
iodo
Quality Level
Application
用作以下过程的反应物：
- 铜催化嘌呤与二芳基碘的交叉偶联反应
- 炔芳基硒醚的合成
- 薗头偶联反应制备芳基炔烃
- （芳亚甲基）吲哚的 C-H 官能团化合成
- 苯胺的芳基化
- 可见光光敏系统 - 荧光黄-二（di-Ph 錪鎓）的研究
- 分散光酸直接光解和敏化光解属性的研究
Other Notes
用于亲电苯基化反应（如丙二酸酯和二硫代羧酸酯的反应）的试剂
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Z.-C. Chen et al.
The Journal of Organic Chemistry, 52, 4115-4115 (1987)
The Journal of Organic Chemistry, 4117-4117 (1987)
Synthesis, 723-723 (1988)
Liya Qin et al.
Journal of neuroinflammation, 9, 5-5 (2012-01-14)
Activation of microglia causes the production of proinflammatory factors and upregulation of NADPH oxidase (NOX) that form reactive oxygen species (ROS) that lead to neurodegeneration. Previously, we reported that 10 daily doses of ethanol treatment induced innate immune genes in
Susana Castro et al.
Chemical communications (Cambridge, England), 48(72), 9089-9091 (2012-08-03)
A novel metal-free direct arylation of unbiased arenes with diaryliodonium triflates in a process where the use of solvents and additives is not required has been established.
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