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Merck
CN

43088

二苯基碘酰氯

≥98.0% (AT)

别名:

DPI, NSC 134275

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关于此项目

线性分子式:
(C6H5)2I+Cl-
化学文摘社编号:
分子量:
316.57
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-049-8
Beilstein/REAXYS Number:
3574977
MDL number:
Assay:
≥98.0% (AT)
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InChI key

RSJLWBUYLGJOBD-UHFFFAOYSA-M

InChI

1S/C12H10I.ClH/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12;/h1-10H;1H/q+1;/p-1

SMILES string

[Cl-].[I+](c1ccccc1)c2ccccc2

assay

≥98.0% (AT)

reaction suitability

reagent type: oxidant

mp

233-235 °C (subl.) (lit.)

functional group

iodo

Quality Level

Application

用作以下过程的反应物:
  • 铜催化嘌呤与二芳基碘的交叉偶联反应
  • 炔芳基硒醚的合成
  • 薗头偶联反应制备芳基炔烃
  • (芳亚甲基)吲哚的 C-H 官能团化合成
  • 苯胺的芳基化
  • 可见光光敏系统 - 荧光黄-二(di-Ph 錪鎓)的研究
  • 分散光酸直接光解和敏化光解属性的研究

Other Notes

用于亲电苯基化反应(如丙二酸酯和二硫代羧酸酯的反应)的试剂

pictograms

Skull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The Journal of Organic Chemistry, 4117-4117 (1987)
Synthesis, 723-723 (1988)
Z.-C. Chen et al.
The Journal of Organic Chemistry, 52, 4115-4115 (1987)
Qiang Ye et al.
Dental materials : official publication of the Academy of Dental Materials, 25(4), 452-458 (2008-11-26)
Our previous study showed poor mechanical durability and nano-sized heterogeneities in cross-linked dentin adhesives cured in the presence of water. To further explore the relationship between nano-scale heterogeneities and the long-term mechanical properties of dentin adhesives, the properties of model
Li Qian et al.
Parkinsonism & related disorders, 13 Suppl 3, S316-S320 (2008-11-19)
In this paper we report that diphenyliodonium (DPI), a NADPH oxidase inhibitor, shows potent anti-inflammatory and neuroprotective effects at femtomolar concentrations (10(-13) to 10(-14) M) in primary midbrain cultures. Mechanistic studies revealed that DPI-elicited effects were mediated by the inhibition

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