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429120

Sigma-Aldrich

3-甲氧基溴苄

98%

别名:

1-溴甲基-3-甲氧基苯

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About This Item

线性分子式:
CH3OC6H4CH2Br
CAS号:
874-98-6
分子量:
201.06
MDL编号:
MFCD00216590
UNSPSC代码:
12352100
PubChem化学物质编号:
24866839
NACRES:
NA.22

质量水平

100

方案

98%

表单

liquid

折射率

n20/D 1.575 (lit.)

沸点

152 °C (lit.)

密度

1.436 g/mL at 25 °C (lit.)

官能团

bromo

SMILES字符串

COc1cccc(CBr)c1

InChI

1S/C8H9BrO/c1-10-8-4-2-3-7(5-8)6-9/h2-5H,6H2,1H3

InChI key

ZKSOJQDNSNJIQW-UHFFFAOYSA-N

相关类别

一般描述

3-甲氧基苄基溴是一种苄基溴衍生物。

应用

3-甲氧基苄基溴（1-溴甲基-3-甲氧基苯）可用于手性琥珀酸衍生物的邻位二价阴离子的非对映选择性烷基化。
它可用于合成以下物质：
  • 6-(3-甲氧基苯基)-己烷-2,4-二酮
  • N-(3-甲氧基苄基)-N-(1-甲基-1-苯乙基)-胺
  • 2-(3-甲氧基苄基)-3-[(1R)-7,7-二甲基-2-氧代双环[2.2.1]庚-1-基]-(3S)-2-硫代双环[2.2.1]-庚烷四氟硼酸盐
  • 1-(3-甲氧基苄基)-5-(1-甲基-1H-咪唑-5-基)-1H-1,2,3-三唑

象形图

Corrosion
GHS05

警示用语：

Danger

危险声明

H314

危险分类

Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

235.4 °F - closed cup

闪点(°C)

113 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCL8646
MKBT8591V
MKBL8798V
MKBF5585V
MKBF5585

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Yang Zhang et al.
The Journal of organic chemistry, 71(12), 4516-4520 (2006-06-06)
A mild protocol for the conversion of beta-ketoesters and beta-diketones to carboxylic acids with use of CAN in CH3CN is described. The method is compatible with a number of functional groups, and can generate carboxylic acids under neutral conditions at
Highly diastereoselective alkylation of vicinal dianions of chiral succinic acid derivatives: a new general strategy to (R)-?-arylmethyl-?-butyrolactones.
Pohmakotr M, et al.
Tetrahedron Letters, 45(22), 4315-4318 (2004)
Synthesis of (-)-kainic acid using chiral lithium amides in an asymmetric dearomatizing cyclization.
Clayden J, et al.
Tetrahedron, 58(23), 4727-4733 (2002)
Application of sulfur ylide mediated epoxidations in the asymmetric synthesis of ?-hydroxy-d-lactones. Synthesis of a mevinic acid analogue and (+)-prelactone B.
Aggarwal VK, et al.
Tetrahedron Asymmetry, 60(43), 9725-9733 (2004)
Johan R Johansson et al.
The Journal of organic chemistry, 76(7), 2355-2359 (2011-03-11)
An experimentally simple sequential one-pot RuAAC reaction, affording 1,5-disubstituted 1H-1,2,3-triazoles in good to excellent yields starting from an alkyl halide, sodium azide, and an alkyne, is reported. The organic azide is formed in situ by treating the primary alkyl halide
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