所有图片(1)
About This Item
线性分子式:
CF3SO3C10H7
CAS号:
分子量:
276.23
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
推荐产品
方案
97%
表单
solid
mp
30-32 °C (lit.)
官能团
fluoro
triflate
SMILES字符串
FC(F)(F)S(=O)(=O)Oc1ccc2ccccc2c1
InChI
1S/C11H7F3O3S/c12-11(13,14)18(15,16)17-10-6-5-8-3-1-2-4-9(8)7-10/h1-7H
InChI key
MDWRQYBWVTXIIJ-UHFFFAOYSA-N
一般描述
2-Naphthyl trifluoromethanesulfonate (2-naphthyl triflate) is an aryl triflate. Its ruthenium-catalyzed conversion to 2-bromonaphthalene has been reported.
应用
2-Naphthyl trifluoromethanesulfonate (2-naphthyl triflate) may be used as an arylating agent in the arylation of 1-(methoxycarbonyl)-2,5-dihydropyrrole by Heck reaction. It may be used as a substrate for coupling with Reformatsky reagent BrZnCH(CH3)(COOtC4H9) in the presence of “reduced” dichlorobis(1,1-diphenylphosphino)ferrocene catalyst.
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
Regiochemical control and suppression of double bond isomerization in the Heck arylation of 1-(methoxycarbonyl)-2, 5-dihydropyrrole.
Sonesson C, et al.
The Journal of Organic Chemistry, 61(14), 4756-4763 (1996)
Influence of the catalyst on the Pd0-mediated reactions of BrZnCH(CH3) COOtBu with vinyl and aryl triflates.
Orsini F, et al.
Journal of Organometallic Chemistry, 367(3), 375-382 (1989)
Xiaoqiang Shen et al.
Journal of the American Chemical Society, 132(40), 14076-14078 (2010-09-23)
The palladium-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) has been developed using dialkylbiaryl phosphine ligands. A variety of aryl, heteroaryl, and vinyl halides can be prepared via this method in good to
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系技术服务部门