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质量水平
方案
99%
表单
solid
mp
63-65 °C (lit.)
官能团
amine
nitro
phenyl
储存温度
2-8°C
SMILES字符串
[H]\C(=C(\C)[N+]([O-])=O)c1ccccc1
InChI
1S/C9H9NO2/c1-8(10(11)12)7-9-5-3-2-4-6-9/h2-7H,1H3/b8-7+
InChI key
WGSVFWFSJDAYBM-BQYQJAHWSA-N
一般描述
反式-β-甲基-β-硝基苯乙烯(1-苯基-2-硝基丙烯),一种硝基苯乙烯衍生物,是 α,β-二取代的硝基烯烃。它是通过苯甲醛与硝基乙烷和丁胺反应合成的。使用 FT-IR、FT-Raman、NMR 和 UV 对 1-苯基-2-硝基丙烯进行了光谱分析。
警示用语:
Warning
危险声明
危险分类
Acute Tox. 4 Oral
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Chemical & pharmaceutical bulletin, 38(12), 3449-3451 (1990-12-01)
Microbial reduction of 1-phenyl-2-nitro-1-propene (3) was carried out using 57 strains of yeast, 40 strains of aerobic and facultatively anaerobic bacteria and 40 strains of strictly anaerobic bacteria. Nine strains of yeast (Candida tropicalis, etc.,) had the ability to reduce
Organocatalytic diastereo- and enantioselective sulfa-Michael addition to α,β-disubstituted nitroalkenes
Tetrahedron, 69, 5367-5373 (2013)
Green Syntheses, 119-119 (2014)
Microbial cell factories, 13, 60-60 (2014-04-29)
Old Yellow Enzymes (OYEs) are flavin-dependent enoate reductases (EC 1.6.99.1) that catalyze the stereoselective hydrogenation of electron-poor alkenes. Their ability to generate up to two stereocenters by the trans-hydrogenation of the C = C double bond is highly demanded in asymmetric synthesis.
Gas chromatographic and mass spectral analysis of amphetamine products synthesized from 1-phenyl-2-nitropropene.
Journal of Chromatographic Science, 32(11), 511-519 (1994)
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