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About This Item
经验公式（希尔记法）:
C5H8O3
CAS号:
分子量:
116.12
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
99%
折射率
n20/D 1.418 (lit.)
沸点
62-65 °C/32 mmHg (lit.)
密度
1.097 g/mL at 25 °C (lit.)
官能团
ester
ether
SMILES字符串
COC(=O)C1(C)CO1
InChI
1S/C5H8O3/c1-5(3-8-5)4(6)7-2/h3H2,1-2H3
InChI key
OSYXXQUUGMLSGE-UHFFFAOYSA-N
一般描述
Methyl 2-methylglycidate (methyl 2-methyloxirane-2-carboxylate) is an ester derived epoxide. It is reported to be formed by the reaction of methyl pyruvate with diazomethane. It is formed as an intermediate in the synthesis of 1,2,4-oxadiazole derivatives.
应用
Methyl 2-methylglycidate may be used in the synthesis of:
- 2-methyl-2-hydroxy-1-propanol
- 2,3-dihydroxy-2-methyl propionic acid
- methyl 2-hydroxy-3-((4-methoxyphenyl)sulfonyl)-2-methylpropanoate
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
129.2 °F - closed cup
闪点(°C)
54 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
β-Keto phosphonic esters.
Arbuzov BA, et al.
Russian Chemical Bulletin, 12(4), 604-610 (1963)
DABSO-Based, Three-Component, One-Pot Sulfone Synthesis.
Deeming AS, et al.
Organic Letters, 16(1), 150-153 (2013)
Gopal L Khatik et al.
Bioorganic & medicinal chemistry letters, 22(5), 1912-1916 (2012-02-14)
Sulfide and sulfonyl derivatives of 1,2,4-oxadiazoles were synthesized and screened by MTT assay on the prostate cancer cells, DU-145. Six compounds were identified as potential anti-prostate cancer agents with IC(50) values ranging from 0.5 to 5.1μM. These compounds exhibited good
R J Steffan et al.
Applied and environmental microbiology, 63(11), 4216-4222 (1997-11-15)
Several propane-oxidizing bacteria were tested for their ability to degrade gasoline oxygenates, including methyl tert-butyl ether (MTBE), ethyl tert-butyl ether (ETBE), and tert-amyl methyl ether (TAME). Both a laboratory strain and natural isolates were able to degrade each compound after
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