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方案
97%
表单
liquid
折射率
n20/D 1.54 (lit.)
沸点
101-102 °C/12 mmHg (lit.)
密度
1.021 g/mL at 25 °C (lit.)
官能团
hydroxyl
phenyl
SMILES字符串
OC(C=C)c1ccccc1
InChI
1S/C9H10O/c1-2-9(10)8-6-4-3-5-7-8/h2-7,9-10H,1H2
InChI key
MHHJQVRGRPHIMR-UHFFFAOYSA-N
一般描述
α-乙烯基苄醇是一种烯丙醇衍生物。已经报道了使用新型三元催化剂体系催化其异构化反应。 已经报道了使用钨催化的不对称环氧化方法对外消旋α-乙烯基苄醇进行动力学拆分。 已经研究了在RuCl2(PPh3)3 催化剂存在下并且使用In(OAc)3作为共催化剂,α乙烯基苄醇和醛在离子液体中的偶联反应。 已经报道了在二氧化硅固载磺酸(SiO2–SO3H)催化剂催化下,甘油与α-乙烯基苄醇的醚化反应。
应用
α−乙烯基苄醇与醇反应,可合成肉桂基醚。
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
201.2 °F - closed cup
闪点(°C)
94 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
历史批次信息供参考:
分析证书(COA)
Ruthenium-catalyzed tandem olefin migration-Aldol-and mannich-type reactions in ionic liquid.
J. Mol. Catal. A: Chem., 214(1), 147-154 (2004)
Journal of the American Chemical Society, 127(17), 6172-6173 (2005-04-28)
Highly efficient isomerization of allylic alcohols into saturated carbonyls is accomplished using the catalyst system of Cp*RuCl[Ph2P(CH2)2NH2-kappa2-P,N]-KOt-Bu (Cp* = eta5-C5(CH3)5) under mild conditions. Mechanistic consideration based on isotope-labeling experiments indicated the present reaction is applicable to the asymmetric isomerization of
Journal of the American Chemical Society, 136(4), 1222-1225 (2014-01-16)
A simple, efficient, and environmentally friendly asymmetric epoxidation of primary, secondary, tertiary allylic, and homoallylic alcohols has been accomplished. This process was promoted by a tungsten-bishydroxamic acid complex at room temperature with the use of aqueous 30% H2O2 as oxidant
Journal of oleo science, 59(10), 549-555 (2010-09-30)
Reactions of α-vinylbenzyl alcohol with other alcohols using iodine as a catalyst were investigated. The corresponding cinnamyl ethers were obtained as products. This suggested that α-vinylbenzyl alcohol was converted to cinnamyl ethers via 1-phenylallyl cation. Cinnamyl ethyl ether was obtained
Heterogeneously catalyzed etherification of glycerol: new pathways for transformation of glycerol to more valuable chemicals.
Green Chemistry, 10(2), 164-167 (2008)
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