质量水平
检测方案
99%
mp
180-184 °C (lit.)
SMILES字符串
Clc1cc(C#N)c(cc1Cl)C#N
InChI
1S/C8H2Cl2N2/c9-7-1-5(3-11)6(4-12)2-8(7)10/h1-2H
InChI key
SRIJSZQFAMLVQV-UHFFFAOYSA-N
一般描述
4,5-二氯邻苯二甲腈（4,5-二氯-1,2-二氰基苯）是邻苯二甲腈的衍生物。它是由 4,5-二氯-1,2-苯二甲酰胺合成的，并经 1H 、13C-NMR 和 IR 表征。4,5-二氯邻苯二甲腈与 O-，S-亲核体和酸性含 -CH 的化合物进行碱催化的亲核芳族取代反应，形成相应的邻苯二甲腈衍生物，它们是酞菁合成中的前体。
应用
4,5-二氯邻苯二甲腈适合用作合成 4,5-双（3,4-二甲氧基苯基）邻苯二甲腈和 4,5-双（2,6-二甲氧基苯氧基）邻苯二甲腈的反应物。它可用于合成 4,5-二苯氧基邻苯二甲腈。
警示用语：
Warning
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
A simple synthesis of 4,5-disubstituted 1,2-dicyanobenzenes and 2,3,9,10,16,17,23,24-octasubstituted phthalocyanines.
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Sterically demanded unsymmetrical zinc phthalocyanines for dye-sensitized solar cells.
Giribabu L, et al.
Dyes and Pigments, 98(3), 518-529 (2013)
Discotic liquid crystals of transition metal complexes 37*: a thermotropic cubic mesophase having Pn m symmetry exhibited by phthalocyanine-based derivatives.
Ichihara M, et al.
Liq. Cryst., 34(5), 555-567 (2007)
Narendran Rajendran et al.
Environmental research, 182, 109001-109001 (2019-12-17)
A microporous organic polymer (Cz-pyr-P) was prepared from a monomer of pyridine-imides, flanked by four carbazoles, and its application as an adsorbent for both CO2 and methylene blue dye in wastewater was investigated. The polymer was synthesised by oxidative polymerisation
A novel route to 4-chloro-5-alkyl-phthalonitrile and phthalocyanines derived from it.
Dincer, HA, et al.
Journal of Porphyrins and Phthalocyanines, 8(10), 1204-1208 (2004)
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