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蒸汽密度
2.9 (vs air)
蒸汽压
7.9 mmHg ( 20 °C)
形式
liquid
自燃温度
590 °F
包含
copper sulfate as stabilizer
折射率
n20/D 1.439 (lit.)
bp
69-70 °C/100 mmHg (lit.)
密度
1.09 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
C=C1CC(=O)O1
InChI
1S/C4H4O2/c1-3-2-4(5)6-3/h1-2H2
InChI key
WASQWSOJHCZDFK-UHFFFAOYSA-N
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应用
用于乙酰乙酸衍生物和杂环化合物的简易制备。
警示用语:
Danger
危险声明
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3
WGK
WGK 1
闪点(°F)
93.2 °F
闪点(°C)
34 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Identification of essential amino acid residues in clostridium histolyticum collagenase using chemical modification reactions.
Biochemical and biophysical research communications, 102(1), 243-249 (1981-09-16)
Journal of combinatorial chemistry, 11(3), 481-485 (2009-04-23)
A convenient synthetic protocol was elaborated for creation of combinatorial libraries of 1-(R(1)-phenyl)-5-methyl-N-R(2)-1H-1,2,3-triazole-4-carboxamides. As starting materials, commercially available or readily prepared azides, amines, and diketene were selected for the reaction which has proceeded in a one-pot system with high yields
The journal of physical chemistry. A, 116(9), 2131-2140 (2012-01-26)
Diketene (C(4)H(4)O(2)) monomers were isolated in cryogenic Ar (15 K) and Xe (30 K) matrices. The infrared (IR) spectra of the freshly deposited matrices show that diketene monomers exclusively adopt the 4-methylene-oxetan-2-one form. In situ photochemical transformations of diketene were
Journal of combinatorial chemistry, 11(3), 375-377 (2009-03-14)
In this work, 1,2,3,4,5,8-hexahydro-1,3,7-trimethyl-2,4-dioxopyrido[2,3-d]pyrimidine-6-carboxamide derivatives were synthesized in a simple and efficient method from the four-component condensation reaction of diketene, an aliphatic or aromatic amine, an aromatic aldehyde, and 6-amino-1,3-dimethyluracil in the presence of a catalytic amount of p-toluenesulfonic acid
Biochimica et biophysica acta, 983(2), 193-198 (1989-08-07)
The hemolytic activity exhibited by the coelomic fluid of the Annelid Eisenia fetida andrei is mediated by two lipoproteins of mass 40 and 45 kDa, each of them capable of hemolysis. Such an activity is not inhibited by zymosan, inulin
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