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Merck
CN

422363

Sigma-Aldrich

双乙烯酮

contains copper sulfate as stabilizer

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经验公式(希尔记法):
C4H4O2
CAS号:
分子量:
84.07
Beilstein:
104541
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:

蒸汽密度

2.9 (vs air)

蒸汽压

7.9 mmHg ( 20 °C)

形式

liquid

自燃温度

590 °F

包含

copper sulfate as stabilizer

折射率

n20/D 1.439 (lit.)

bp

69-70 °C/100 mmHg (lit.)

密度

1.09 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES字符串

C=C1CC(=O)O1

InChI

1S/C4H4O2/c1-3-2-4(5)6-3/h1-2H2

InChI key

WASQWSOJHCZDFK-UHFFFAOYSA-N

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应用

用于乙酰乙酸衍生物和杂环化合物的简易制备。

象形图

FlameSkull and crossbones

警示用语:

Danger

危险声明

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3

WGK

WGK 1

闪点(°F)

93.2 °F

闪点(°C)

34 °C

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Identification of essential amino acid residues in clostridium histolyticum collagenase using chemical modification reactions.
M D Bond et al.
Biochemical and biophysical research communications, 102(1), 243-249 (1981-09-16)
Nazariy T Pokhodylo et al.
Journal of combinatorial chemistry, 11(3), 481-485 (2009-04-23)
A convenient synthetic protocol was elaborated for creation of combinatorial libraries of 1-(R(1)-phenyl)-5-methyl-N-R(2)-1H-1,2,3-triazole-4-carboxamides. As starting materials, commercially available or readily prepared azides, amines, and diketene were selected for the reaction which has proceeded in a one-pot system with high yields
S Breda et al.
The journal of physical chemistry. A, 116(9), 2131-2140 (2012-01-26)
Diketene (C(4)H(4)O(2)) monomers were isolated in cryogenic Ar (15 K) and Xe (30 K) matrices. The infrared (IR) spectra of the freshly deposited matrices show that diketene monomers exclusively adopt the 4-methylene-oxetan-2-one form. In situ photochemical transformations of diketene were
Ahmad Shaabani et al.
Journal of combinatorial chemistry, 11(3), 375-377 (2009-03-14)
In this work, 1,2,3,4,5,8-hexahydro-1,3,7-trimethyl-2,4-dioxopyrido[2,3-d]pyrimidine-6-carboxamide derivatives were synthesized in a simple and efficient method from the four-component condensation reaction of diketene, an aliphatic or aromatic amine, an aromatic aldehyde, and 6-amino-1,3-dimethyluracil in the presence of a catalytic amount of p-toluenesulfonic acid
P Roch et al.
Biochimica et biophysica acta, 983(2), 193-198 (1989-08-07)
The hemolytic activity exhibited by the coelomic fluid of the Annelid Eisenia fetida andrei is mediated by two lipoproteins of mass 40 and 45 kDa, each of them capable of hemolysis. Such an activity is not inhibited by zymosan, inulin

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