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方案
98%
mp
101-104 °C (lit.)
SMILES字符串
S[Si](c1ccccc1)(c2ccccc2)c3ccccc3
InChI
1S/C18H16SSi/c19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H
InChI key
MQDRKELSDPESDZ-UHFFFAOYSA-N
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一般描述
Triphenylsilanethiol, also known as triphenylsilyl mercaptan, is an organosilicon compound that is commonly used as a reagent in organic synthesis. It can be used as a reagent for palladium-catalyzed cross-coupling reactions, such as the Stille coupling and the Sonogashira coupling reactions.
应用
Triphenylsilanethiol can be used as:
- A reactant to synthesis β-hydroxymercaptans or β-dihydroxysulfides by ring opening of epoxides.
- An additive in the selective C–H bond functionalization of widely available trialkylamine scaffolds.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
从最新的版本中选择一种:
分析证书(COA)
Tetrahedron Letters, 34, 3363-3363 (1993)
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