所有图片(3)
About This Item
线性分子式:
C6H10(OH)2
CAS号:
分子量:
116.16
Beilstein:
1901343
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
99%
旋光性
[α]20/D +39°, c = 1.6 in H2O
光学纯度
ee: 99% (GLC)
mp
107-109 °C (lit.)
官能团
hydroxyl
SMILES字符串
O[C@H]1CCCC[C@@H]1O
InChI
1S/C6H12O2/c7-5-3-1-2-4-6(5)8/h5-8H,1-4H2/t5-,6-/m0/s1
InChI key
PFURGBBHAOXLIO-WDSKDSINSA-N
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应用
C2-对称手性二醇，具有多种用途如手性助剂、结构单元和手性配体。
(1S,2S)-trans-1,2-Cyclohexanediol may be used in the preparation of (1S,2S)-1,2-cyclohexanediyl bis(4-vinylbenzoate) by reacting with 4-vinylbenzoyl chloride. It may also be used as a chiral ligand for the preparation of non-racemic hydroxy phosphonates via titanium alkoxide-catalyzed addition of dimethyl phosphite to the corresponding aldehydes.
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - STOT SE 3
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
The synthesis of 1-hydroxy phosphonates of high enantiomeric excess using sequential asymmetric reactions: titanium alkoxide-catalyzed P C bond formation and kinetic resolution.
Rowe BJ and Spilling CD.
Tetrahedron Asymmetry, 12(12), 1701-1708 (2001)
Chirality induction in cyclocopolymerization. 14. Template effect of 1, 2-cycloalkanediol in the cyclocopolymerization of bis (4-vinylbenzoate) s with styrene.
Kakuchi T, et al.
Macromolecules, 34(1), 38-43 (2001)
Marshall, J.A. Xie, S.
The Journal of Organic Chemistry, 60, 7230-7230 (1995)
Stolle, A. et al.
Tetrahedron Letters, 35, 3521-3521 (1994)
Ho, O.C. et al.
Organometallics, 14, 2855-2855 (1995)
Chromatograms
suitable for GC我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
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