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Merck
CN

42140

Sigma-Aldrich

2,7-二硝基甲酚

≥95.0% (HPLC)

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经验公式(希尔记法):
C10H6N2O4
CAS号:
分子量:
218.17
Beilstein:
2214687
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:

检测方案

≥95.0% (HPLC)

mp

229-233 °C

SMILES字符串

[O-][N+](=O)c1ccc2ccc(cc2c1)[N+]([O-])=O

InChI

1S/C10H6N2O4/c13-11(14)9-3-1-7-2-4-10(12(15)16)6-8(7)5-9/h1-6H

InChI key

AFDWAIQLYHEUIW-UHFFFAOYSA-N

一般描述

Kinetics and ESR studies of intramolecular electron-transfer reactions of the radical anion of 2,7-dinitronaphthalene in various polar aprotic solvents has been studied. 2,7-Dinitronaphthalene undergoes mononitration to afford 1:3:6:8-tetranitronapthalene.

应用

2,7-Dinitronaphthalene has been used for the cyclodextrin distribution capillary electrochromatographic separation of naphthalene compounds.

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves

法规信息

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107. The further nitration of 1: 3-, 1: 6-, 2: 6-, and 2: 7-dinitronaphthalenes, and the preparation of 1: 3: 6-trinitronaphthalene.
Edward, R.
Journal of the Chemical Society, 533-534 (1946)
M Culha et al.
Analytical chemistry, 72(1), 88-95 (2000-02-03)
Separations of naphthalene compounds that differ in position of substitution and type of substituent were accomplished using cyclodextrin distribution capillary electrochromatography. Separation systems composed of running buffers containing mixtures of native neutral and single isomer anionic cyclodextrins (CDs) were employed
João P Telo et al.
The journal of physical chemistry. A, 113(27), 7730-7736 (2009-06-10)
Rate constants for the intramolecular electron-transfer reaction in the 2,7-dinitronaphthalene (2(-)), 4,4'-dinitrotolane (3(-)), and 2,2'-dimethyl-4,4'-dinitrobiphenyl (4(-)) radical anions in several polar aprotic solvents were estimated by simulating their ESR spectra at different temperatures. At 298 K, the rate constants are

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