推荐产品
等级
technical grade
质量水平
检测方案
90%
形式
powder
mp
>300 °C (lit.)
SMILES字符串
[Na]Sc1ccccc1
InChI
1S/C6H6S.Na/c7-6-4-2-1-3-5-6;/h1-5,7H;/q;+1/p-1
InChI key
RZWQDAUIUBVCDD-UHFFFAOYSA-M
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一般描述
硫酚钠可由硫酚钠在乙醚中与硫酚反应制得。
应用
硫酚钠已用于合成 MCoTI-I 和 MCoTI-II 环肽，它们是天然存在的环胱氨酸结微量蛋白胰蛋白酶抑制剂。可用于以下研究：
- 作为免疫分析和表面增强拉曼散射 (SERS) 检测无标记蛋白质的探针。
- 新型环金属化合物 6-苯基-4-（ p - R -苯基）-2,2′ 的制备-联吡啶 (C-N-N) Pt (II) 硫代酚盐复合物。
- 1，3，5，7，9-五（4-甲氧基苯基硫基）松油烯、1，3，5，7，9-五（2-萘硫基）松油烯和 1，3，6，8-四（4-甲氧基苯基硫基）松油烯的合成。
- 芳基硫醇钛 (Ⅳ) 配合物 Et4N+ 盐的合成，[Ti(SPh)6]2-。
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
S Mizyed et al.
Journal of the American Chemical Society, 123(51), 12770-12774 (2001-12-26)
1,3,5,7,9-Pentakis(4-methoxyphenylthio)corannulene (3), 1,3,5,7,9-pentakis(2-naphthylthio)corannulene (4), and 1,3,6,8-tetrakis(4-methoxyphenylthio)corannulene (5b) have been synthesized by chlorination of corannulene with ICl in CH(2)Cl(2) at 25 degrees C and subsequent nucleophilic aromatic substitution with the appropriate sodium thiophenolate in DMEU at 25 degrees C. (1)H NMR
Jacob Schneider et al.
Inorganic chemistry, 48(4), 1498-1506 (2009-01-15)
Three new cyclometalated 6-phenyl-4-(p-R-phenyl)-2,2'-bipyridyl (C--N--N) Pt(II) thiophenolate complexes (R = Me (2a), COOMe (2b), and P(O)(OEt)(2) (2c)) have been synthesized and studied. The new C--N--N ligands L2 (R = COOMe) and L3 (R = P(O)(OEt)(2)) undergo cyclometalation with a Pt(II)
Panumart Thongyoo et al.
Organic & biomolecular chemistry, 6(8), 1462-1470 (2008-04-04)
The naturally-occurring cyclic cystine-knot microprotein trypsin inhibitors MCoTI-I and MCoTI-II have been synthesised using both thia-zip native chemical ligation and a biomimetic strategy featuring chemoenzymatic cyclisation by an immobilised protease. Engineered analogues have been produced containing a range of substitutions
Xuefang Gu et al.
Analytical and bioanalytical chemistry, 406(7), 1885-1894 (2014-03-01)
A simple and sensitive method, based on surface-enhanced Raman scattering (SERS), for immunoassay and label-free protein detection is reported. A series of bowl-shaped silver cavity arrays were fabricated by electrodeposition using a self-assembled polystyrene spheres template. The reflection spectra of
The synthesis and structural characterization of [Et4N]2 [Ti(SPh)6] and trimeric [Ti3O(SPh)3Cl4 (CH3 CN)5]?CH3 CN?(C2 H5)2O complexes.
Kim JT, et al.
Polyhedron, 19(9), 1139-1143 (2000)
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