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质量水平
方案
97%
旋光性
[α]22/D +20°, c = 12 in THF
沸点
>55 °C (lit.)
密度
0.947 g/mL at 25 °C (lit.)
SMILES字符串
C[C@@H]1[C@H](CC2CC1C2(C)C)B3C4CCCC3CCC4
InChI
1S/C18H31B/c1-12-16-10-13(18(16,2)3)11-17(12)19-14-6-4-7-15(19)9-5-8-14/h12-17H,4-11H2,1-3H3/t12-,13+,14-,15+,16-,17-/m0/s1
InChI key
VCDGSBJCRYTLNU-NEXGVSGLSA-N
一般描述
S-Alpine-Borane® is a chiral reducing agent, synthesized from (-)-α-pinene via hydroboration.
应用
S-Alpine-Borane® may be used in the preparation of (-)-(4S)-5-methyl-2-hexyn-4-ol, an intermediate for the synthesis of (+)-Prelog-Djerassi lactonic aldehyde.
法律信息
Alpine-Borane is a registered trademark of Merck KGaA, Darmstadt, Germany
警示用语：
Danger
危险声明
预防措施声明
危险分类
Pyr. Liq. 1
储存分类代码
4.2 - Pyrophoric and self-heating hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Application of [2,3] sigmatropic (Wittig) rearrangements in synthesis. The synthesis of (+)-Prelog-Djerassi lactone.
Tsai DJS, and Midland MM.
Journal of the American Chemical Society, 107(13), 3915-3918 (1985)
Matteson DS
Stereodirected Synthesis with Organoboranes, 346-347 (2012)
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