质量水平
检测方案
97%
形式
liquid
折射率
n20/D 1.421 (lit.)
bp
162-164 °C (lit.)
密度
0.873 g/mL at 25 °C (lit.)
SMILES字符串
CCCCCCN=C=O
InChI
1S/C7H13NO/c1-2-3-4-5-6-8-7-9/h2-6H2,1H3
InChI key
ANJPRQPHZGHVQB-UHFFFAOYSA-N
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一般描述
异氰酸己酯的抗原性已在半抗原特异性呼吸道超敏反应的豚鼠动物模型中进行了研究。 以稀土三（2,6-二-叔-丁基-4-甲基苯酚酯）[Ln（OAr）3]为引发剂，异氰酸正己酯的聚合反应已有研究。
应用
异氰酸己酯可用于以下合成：
- 刚性杆状、螺旋异氰酸酯基大分子单体
- 利用活性阴离子聚合制备具有2-乙烯基吡啶的棒-卷-棒三嵌段共聚物
- 通过活性阴离子聚合制备手性聚（n-己基异氰酸酯）（PHIC）大分子单体
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3 - Resp. Sens. 1 - Skin Sens. 1
WGK
WGK 3
闪点(°F)
closed cup
闪点(°C)
closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Chiroptical Properties of Graft Copolymers Containing Chiral Poly (n-hexyl isocyanate) as a Side Chain.
Shah PN, et al.
Macromolecules, 44(20), 7917-7925 (2011)
Garret M Miyake et al.
Journal of the American Chemical Society, 134(34), 14249-14254 (2012-08-16)
The synthesis of rigid-rod, helical isocyanate-based macromonomers was achieved through the polymerization of hexyl isocyanate and 4-phenylbutyl isocyanate, initiated by an exo-norbornene functionalized half-titanocene complex. Sequential ruthenium-mediated ring-opening metathesis polymerization of these macromonomers readily afforded well-defined brush block copolymers, with
Synthesis and Self-Assembly Studies of Amphiphilic Poly (n-hexyl isocyanate)-b lock-poly (2-vinylpyridine)-b lock-poly (n-hexyl isocyanate) Rod-Coil-Rod Triblock Copolymer.
Rahman M, et al.
Macromolecules, 39(15), 5009-5014 (2006)
Pulmonary hypersensitivity to hexyl isocyanate-ovalbumin aerosol in guinea pigs.
M H Karol et al.
Toxicology and applied pharmacology, 51(1), 73-80 (1979-10-01)
Boer Liu et al.
Molecules (Basel, Switzerland), 26(15) (2021-08-08)
This work reveals the influence of pendant hydrogen bonding strength and distribution on self-assembly and the resulting thermomechanical properties of A-AB-A triblock copolymers. Reversible addition-fragmentation chain transfer polymerization afforded a library of A-AB-A acrylic triblock copolymers, wherein the A unit
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