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质量水平
方案
97%
表单
liquid
折射率
n20/D 1.421 (lit.)
沸点
162-164 °C (lit.)
密度
0.873 g/mL at 25 °C (lit.)
官能团
amine
isocyanate
SMILES字符串
CCCCCCN=C=O
InChI
1S/C7H13NO/c1-2-3-4-5-6-8-7-9/h2-6H2,1H3
InChI key
ANJPRQPHZGHVQB-UHFFFAOYSA-N
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一般描述
异氰酸己酯的抗原性已在半抗原特异性呼吸道超敏反应的豚鼠动物模型中进行了研究。 以稀土三（2,6-二-叔-丁基-4-甲基苯酚酯）[Ln（OAr）3]为引发剂，异氰酸正己酯的聚合反应已有研究。
应用
异氰酸己酯可用于以下合成：
- 刚性杆状、螺旋异氰酸酯基大分子单体
- 利用活性阴离子聚合制备具有2-乙烯基吡啶的棒-卷-棒三嵌段共聚物
- 通过活性阴离子聚合制备手性聚（n-己基异氰酸酯）（PHIC）大分子单体
警示用语：
Danger
危险分类
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3 - Resp. Sens. 1 - Skin Sens. 1
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
138.2 °F - closed cup
闪点(°C)
59 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
Pulmonary hypersensitivity to hexyl isocyanate-ovalbumin aerosol in guinea pigs.
M H Karol et al.
Toxicology and applied pharmacology, 51(1), 73-80 (1979-10-01)
Boer Liu et al.
Molecules (Basel, Switzerland), 26(15) (2021-08-08)
This work reveals the influence of pendant hydrogen bonding strength and distribution on self-assembly and the resulting thermomechanical properties of A-AB-A triblock copolymers. Reversible addition-fragmentation chain transfer polymerization afforded a library of A-AB-A acrylic triblock copolymers, wherein the A unit
Synthesis and Self-Assembly Studies of Amphiphilic Poly (n-hexyl isocyanate)-b lock-poly (2-vinylpyridine)-b lock-poly (n-hexyl isocyanate) Rod-Coil-Rod Triblock Copolymer.
Rahman M, et al.
Macromolecules, 39(15), 5009-5014 (2006)
Maresa Sonnabend et al.
Polymers, 13(12) (2021-07-03)
Due to reasons of sustainability and conservation of resources, polyurethane (PU)-based systems with preferably neutral carbon footprints are in increased focus of research and development. The proper design and development of bio-based polyols are of particular interest since such polyols
Chiroptical Properties of Graft Copolymers Containing Chiral Poly (n-hexyl isocyanate) as a Side Chain.
Shah PN, et al.
Macromolecules, 44(20), 7917-7925 (2011)
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