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应用
消除反应试剂
盐酸溶液中铁缓蚀剂的反应物
用于催化：
脂肪胺的制备
消除乙烯酮形成
三氟甲磺酸酯的立体选择性合成
盐酸溶液中铁缓蚀剂的反应物
用于催化：
脂肪胺的制备
消除乙烯酮形成
三氟甲磺酸酯的立体选择性合成
cis-2,6-Dimethylpiperidine [cis-DMP(H)] may be used for the preparation of four new zincates and one new magnesiate, where [TMEDA = N,N,N´,N´-tetramethylethylenediamine; cis-DMP = cis-2,6-dimethylpiperidide; DIBA(H) = diisobutylamine]:
- (TMEDA)·LiZn(cis-DMP)(t Bu)2
- (TMEDA)·NaZn(cis-DMP)(t Bu)2
- (TMEDA)·NaZn(cis-DMP)2(t Bu)
- (TMEDA)·NaZn(DIBA)2(t Bu)
- (TMEDA)·NaMg(cis-DMP)3
警示用语：
Danger
危险分类
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
53.6 °F - closed cup
闪点(°C)
12 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
Anton Vidal-Ferran et al.
The Journal of organic chemistry, 63(18), 6309-6318 (2001-10-24)
Enantiomerically pure (2S,3S)-2,3-epoxy-3-phenylpropanol (3) has been anchored to Merrifield resins with different degrees of cross-linking and functionalization. The resulting epoxy-functionalized resins 4 have been submitted to completely regioselective (C-3 attack) and stereospecific ring-opening with secondary amines [piperidine (a), N-methylpiperazine (b)
Ross Campbell et al.
Dalton transactions (Cambridge, England : 2003), (2)(2), 511-519 (2009-12-22)
Four novel heterobimetallic ate complexes containing cis-2,6-dimethylpiperidide (cis-DMP) have been prepared and characterised. Two contain one cis-DMP ligand, namely the bisalkyl-amido lithium, and sodium zincates [(TMEDA) x MZn(cis-DMP)(tBu)2] (M = Li for 1, Na for 2). Both 1 and 2
Proton magnetic resonance studies of cyclic compounds-VI: Cis-and trans-2, 6-dimethylpiperidine and cis (2, 4), cis (4, 6), cis (2, 6)-2, 4, 6-trimethylpiperidine.
Booth HJ< et al.
Tetrahedron, 24(1), 279-287 (1968)
Dawid Jędrzkiewicz et al.
Polymers, 12(9) (2020-09-04)
An efficient synthesis strategy of a well-defined polylactide-dye conjugate in a controlled fashion is presented. The introduction of coloring species as end groups of polylactide (PLA) has been performed by using new homoleptic aminophenolate magnesium or zinc coordination compounds. The
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