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Merck
CN

410497

Sigma-Aldrich

4-(二氰亚甲基)-2-甲基-6-(4-二甲氨基苯乙烯基)-4 H -吡喃

Dye content 98 %

别名:

DCM

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About This Item

经验公式(希尔记法):
C19H17N3O
CAS号:
分子量:
303.36
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23

表单

solid

质量水平

组成

Dye content, 98%

mp

215-220 °C (lit.)

λmax

468 nm

OLED设备性能

ITO/Alq3:DCM/Alq3/Mg:Ag

  • Color: red
  • Max. EQE: 1.3 %

ITO/TPD/Alq3:DCM (10%)/Alq3/Mg:Ag
  • Color: red
  • Max. Luminance: 150 Cd/m2

SMILES字符串

CN(C)c1ccc(\C=C\C2=CC(\C=C(C)O2)=C(\C#N)C#N)cc1

InChI

1S/C19H17N3O/c1-14-10-16(17(12-20)13-21)11-19(23-14)9-6-15-4-7-18(8-5-15)22(2)3/h4-11H,1-3H3/b9-6+

InChI key

YLYPIBBGWLKELC-RMKNXTFCSA-N

一般描述

4-(二氰甲烯基)-2-甲基-6-(4-二甲氨基苯乙烯基)- 4H -吡喃(DCM)是一种红色激光染料,以二氰甲烯基为电子受体,二甲基苯胺为电子供体。它有一个π-共轭4H -吡喃-4- ylidiene,用于连接受体和供体基团。它可以用作掺杂剂,也可以用于有机固态激光器。

应用

DCM可作为一种激光染料,通过FÖrster共振能量转移(FRET)来增强分布式反馈(DFB)器件的发射。它可被用作覆盖层,允许在有机发光二极管(OLED)中将蓝色发射转换为红色发射。DCM还可能应用在在增强金属有机框架(MOF)、染料敏化太阳能电池(DSSC)和极性传感器等不同器件的能量转移方面。

特点和优势

在聚合物发光二极管 (PLED) 中使用不同量的 DCM 染料,可观察到具有增强亮度(约 1000cd/m2)的电压可调式多色发光。

象形图

FlameExclamation mark

警示用语:

Danger

危险分类

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

4.1B - Flammable solid hazardous materials

WGK

WGK 3

闪点(°F)

109.4 °F - closed cup

闪点(°C)

43 °C - closed cup

个人防护装备

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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分析证书(COA)

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访问文档库

Ashim Pramanik et al.
Journal of colloid and interface science, 565, 326-336 (2020-01-25)
The development of white light-emitting LED (WLED) is now one of the important demands of present society due to its energy saving feature. However, in this work, an ingenious strategy has been employed to develop Forster resonance energy transfer (FRET)
Arnab Halder et al.
Langmuir : the ACS journal of surfaces and colloids, 20(3), 653-657 (2005-03-19)
Solvation dynamics of 4-(dicyanomethylidene)-2-[p-(dimethylamino)styryl]-6-methyl-4H-pyran (DCM) is studied in a polypeptide-surfactant aggregate consisting of gelatin and sodium dodecyl sulfate (SDS) in potassium dihydrogen phosphate (KP) buffer. The average solvation time (tauS) in gelatin-SDS aggregate at 45 degrees C is found to
Tunable two-color luminescence and host-guest energy transfer of fluorescent chromophores encapsulated in metal-organic frameworks.
Yan D, et al.
Scientific reports, 4(3), 4337-4337 (2014)
Solid state solvation effect and reduced amplified spontaneous emission threshold value of glass forming DCM derivative in PMMA films.
Vembris A, et al.
Journal of Luminescence, 158(7), 441-446 (2015)
Tunable organic distributed feedback dye laser device excited through Forster mechanism.
Tsutsumi N and Hinode T
Applied Physics B: Lasers and Optics, 123(3), 93-93 (2017)

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