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Merck
CN

409405

Sigma-Aldrich

氯三(三甲基甲硅烷基)硅烷

97%

别名:

1,1,1,3,3,3-Hexamethyl-2-(trimethylsilyl)-2-chlorotrisilane, 2-Chloro-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane, Tris(trimethylsilyl)chlorosilane, Tris(trimethylsilyl)silyl chloride

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About This Item

线性分子式:
[(CH3)3Si]3SiCl
CAS号:
分子量:
283.11
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22

质量水平

方案

97%

表单

solid

mp

50-52 °C (lit.)

SMILES字符串

C[Si](C)(C)[Si](Cl)([Si](C)(C)C)[Si](C)(C)C

InChI

1S/C9H27ClSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h1-9H3

InChI key

HCOROOJWVHFMRJ-UHFFFAOYSA-N

相关类别

一般描述

Chlorotris(trimethylsilyl)silane is an organosilicon reagent, which is generally employed in the protection of alcohols. It is also used to prepare organometallic reagents, silyl enol ethers, and novel polymers/materials.

应用

Super Silyl Protecting Groups

Used for:
  • Insertion into a P-P bond
  • Diastereoselective aldol and cascade reactions
  • Preparation of hypersilyl substituted monophosphines and diphosphines

象形图

FlameExclamation mark

警示用语:

Danger

危险分类

Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3 - Water-react 3

靶器官

Respiratory system

补充剂危害

储存分类代码

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

闪点(°F)

87.8 °F - closed cup

闪点(°C)

31 °C - closed cup

个人防护装备

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Chlorotris(trimethylsilyl)silane
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2011)
Chlorotris(trimethylsilyl)silane
e-EROS Encyclopedia of Reagents for Organic Synthesis (2011)

相关内容

The Yamamoto group has employed several applications in catalysis.

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