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Merck
CN

409294

Sigma-Aldrich

碘化锡(IV)

anhydrous, powder, 99.999% trace metals basis

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别名:
四碘化锡
线性分子式:
SnI4
CAS号:
分子量:
626.33
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23

等级

anhydrous

质量水平

检测方案

99.999% trace metals basis

形式

powder

杂质

≤15.0 ppm Trace Metal Analysis

密度

4.47 g/mL at 25 °C (lit.)

SMILES字符串

I[Sn](I)(I)I

InChI

1S/4HI.Sn/h4*1H;/q;;;;+4/p-4

InChI key

QPBYLOWPSRZOFX-UHFFFAOYSA-J

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应用


  • Influence of pi-Iodide intermolecular interactions on electronic properties of Tin (IV) iodide semiconducting complexes: This study explores the crystal structure and electronic properties of tin(IV) iodide complexed with organic ligands (E Wlazlak et al., 2016).

  • Origin of Sn (II) oxidation in tin halide perovskites: This research investigates the oxidation mechanisms of Sn(II) to Sn(IV) in tin halide perovskites and its implications on material stability (J Pascual et al., 2020).

  • Fluoride chemistry in tin halide perovskites: The paper discusses the impact of fluoride addition on the coordination and oxidation states of tin centers in iodide perovskites (J Pascual et al., 2021).

  • Mechanochemical synthesis of Sn (II) and Sn (IV) iodide perovskites and study of their structural, chemical, thermal, optical, and electrical properties: This work details the synthesis and characterization of pure-tin and mixed tin-lead iodide perovskites (Y El Ajjouri et al., 2020).

  • Degradation mechanism of hybrid tin-based perovskite solar cells and the critical role of tin (IV) iodide: This study elucidates the degradation mechanisms of tin perovskite solar cells, highlighting the role of tin(IV) iodide in this process (L Lanzetta et al., 2021).

警示用语:

Danger

危险分类

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

法规信息

危险化学品

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Zhibin Yang et al.
Advanced materials (Deerfield Beach, Fla.), 28(40), 8990-8997 (2016-10-21)
A low-bandgap (1.33 eV) Sn-based MA
Nezhueyotl Izquierdo et al.
ACS nano, 13(6), 7091-7099 (2019-05-31)
A single-step, direct silicon-substrate growth of black phosphorus (BP) crystals is achieved in a self-contained short-way transport technique under low-pressure conditions (<1.5 MPa). A 115 nm-thick BP hero single crystal is formed with lateral dimensions of 10 × 85 μm.
Meng Li et al.
Advanced materials (Deerfield Beach, Fla.), 30(20), e1800258-e1800258 (2018-04-01)
Exploiting organic/inorganic hybrid perovskite solar cells (PSCs) with reduced Pb content is very important for developing environment-friendly photovoltaics. Utilizing of Pb-Sn alloying perovskite is considered as an efficient route to reduce the risk of ecosystem pollution. However, the trade-off between
Jia Zhang et al.
Nature communications, 11(1), 2618-2618 (2020-05-28)
Charge-transfer excitons (CTEs) immensely enrich property-tuning capabilities of semiconducting materials. However, such concept has been remaining as unexplored topic within halide perovskite structures. Here, we report that CTEs can be effectively formed in heterostructured 2D perovskites prepared by mixing PEA2PbI4:PEA2SnI4
Satyaprasad P Senanayak et al.
Science advances, 6(15), eaaz4948-eaaz4948 (2020-04-18)
Despite sustained research, application of lead halide perovskites in field-effect transistors (FETs) has substantial concerns in terms of operational instabilities and hysteresis effects which are linked to its ionic nature. Here, we investigate the mechanism behind these instabilities and demonstrate

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