409049
(1,5-环辛二烯)二甲基铂(II)
97%
别名:
Pt(cod)(Me)2, 二甲基（环辛二烯）铂
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选择尺寸
关于此项目
经验公式（希尔记法）:
C10H18Pt
化学文摘社编号:
分子量:
333.33
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
产品名称
(1,5-环辛二烯)二甲基铂(II), 97%
InChI
1S/C8H12.2CH3.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H3;/b2-1-,8-7-;;;
SMILES string
C[Pt]C.C1CC=CCCC=C1
InChI key
ZABVBYGUHBRHFJ-PHFPKPIQSA-N
assay
97%
reaction suitability
core: platinum
reagent type: catalyst
mp
103-105 °C (lit.)
Quality Level
Application
(1,5-环辛二烯)二甲基铂(II)可作为铂前体：
- 在还原剂(NaBH4)存在下制备疏水性铂催化剂。
- Pt/Hβ催化剂可将正丁烷选择性异构化为异丁烷。
General description
(1,5-环辛二烯)二甲基铂(II)为配位化合物，由2个甲基(CH3)和1个1,5-环辛二烯(COD)基团围绕铂(Pt)而成。常作为前体合成铂催化剂广泛用于各种有机反应。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
The controlled synthesis of Pt/H? catalysts with intimate metal-acid sites for n-butane isomerization
Wang P, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 309, 110547-110547 (2020)
Preparation of hydrophobic platinum catalysts using a water-in-CO2 microemulsion
Shimizu R, et al.
Journal of Supercritical Fluids, 44(1), 109-114 (2008)
The room temperature substitution of n-and iso-perfluoropropyl iodides and n-perfluorobutyl iodide to dimethylplatinum (II) 1, 5-cyclooctadiene: The crystal structure of [Pt (C3F7) 2 (COD)]
Thomson J, et al.
Inorganic Chemistry Communications, 8(9), 782-784 (2005)
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