407739
L-叔亮氨醇
98%, for peptide synthesis
别名:
(S)-2-氨基-3,3-二甲基-1-丁醇
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关于此项目
线性分子式:
(CH3)3CCH(NH2)CH2OH
化学文摘社编号:
分子量:
117.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352209
MDL number:
Beilstein/REAXYS Number:
3600321
产品名称
L-叔亮氨醇, 98%
InChI
1S/C6H15NO/c1-6(2,3)5(7)4-8/h5,8H,4,7H2,1-3H3/t5-/m1/s1
SMILES string
CC(C)(C)[C@H](N)CO
InChI key
JBULSURVMXPBNA-RXMQYKEDSA-N
assay
98%
optical activity
[α]26/D +37°, c = 1.5 in ethanol
reaction suitability
reaction type: solution phase peptide synthesis
mp
30-34 °C (lit.)
density
0.9 g/mL at 25 °C (lit.)
application(s)
peptide synthesis
Quality Level
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Application
用于各种不对称反应的有用氨基酸。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
194.0 °F - closed cup
flash_point_c
90 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Tetrahedron, 60, 4459-4473 (2004)
SimplePHOX, a readily available chiral ligand system for iridium-catalyzed asymmetric hydrogenation.
Sebastian P Smidt et al.
Organic letters, 6(12), 2023-2026 (2004-06-05)
[reaction: see text] New Ir-SimplePHOX complexes Ir-6-Ir-9 catalyze the quantitative, highly enantioselective hydrogenation of a range of unfunctionalized and functionalized olefins. Synthesis, catalytic results, and X-ray crystal structures are presented here.
Tetrahedron Letters, 45, 5649-5649 (2004)
Heng Wang et al.
Chirality, 27(8), 523-531 (2015-04-25)
A novel pyridineoxazoline (PyOx) containing helical polymer, poly{(-)-(S)-4-tert-butyl-2-[5-(4-tert-butylphenyl)-3-vinylpyridin-2-yl]-oxazoline} (PA), was designed and synthesized to approach the effect of chain conformation on the catalytic property. Its complex with Cu(OTf)(2) , i.e., Cu(II)-PA, was employed to catalyze the homogeneous Diels-Alder (D-A) reaction
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