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Merck
CN

407275

Sigma-Aldrich

N,N-二甲基苯胺

purified by redistillation, ≥99.5%

别名:

N,N-Dimethylaniline, N,N-Dimethylphenylamine, DMA, Dimethylaniline, Dimethylphenylamine

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About This Item

线性分子式:
C6H5N(CH3)2
CAS号:
分子量:
121.18
Beilstein:
507140
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
方案:
≥99.5%
沸点:
193-194 °C (lit.)

质量水平

方案

≥99.5%

表单

liquid

纯化方式

glass distillation
redistillation

折射率

n20/D 1.557 (lit.)

pH值(酸碱度)

7.4 (20 °C, 1.2 g/L)

沸点

193-194 °C (lit.)

mp

1.5-2.5 °C (lit.)

密度

0.956 g/mL at 25 °C (lit.)

官能团

amine

SMILES字符串

CN(C)c1ccccc1

InChI

1S/C8H11N/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3

InChI key

JLTDJTHDQAWBAV-UHFFFAOYSA-N

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一般描述

通过常规和循环伏安法对在酸性缓冲液中铂电极上N,N-二甲基苯胺的阳极氧化进行了研究。采用皮秒-飞秒激光光解和时间分辨瞬态吸收光谱研究了DMA在乙腈溶液中对兴奋二苯甲酮(BP)的光还原反应。

应用

N,N-二甲基苯胺(DMA)可用于通过DMA的阳极氧化制备聚(N,N-二甲基苯胺)膜。

警示用语:

Danger

危险分类

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Carc. 2

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

闪点(°F)

167.0 °F - closed cup

闪点(°C)

75 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Femtosecond-picosecond laser photolysis studies on photoreduction process of excited benzophenone with N,N-dimethylaniline in acetonitrile solution.
Miyasaka H, et al.
Bulletin of the Chemical Society of Japan, 63(12), 3385-3397 (1990)
Electrochemically polymerized N, N-dimethylaniline film with ion-exchange properties as an electrode modifier.
Oyama N, et al.
Analytical Chemistry, 57(8), 1526-1532 (1985)
Anodic oxidation studies of N,N-dimethylaniline. I. Voltammetric and spectroscopic investigations at platinum electrodes.
Mizoguchi T and Adams RN.
Journal of the American Chemical Society, 84(11), 2058-2061 (1962)
Marius Koch et al.
Journal of the American Chemical Society, 134(8), 3729-3736 (2012-01-31)
The fluorescence quenching of 3-cyanoperylene upon electron transfer from N,N-dimethylaniline in three room-temperature ionic liquids (RTILs) and in binary solvent mixtures of identical viscosity has been investigated using steady-state and time-resolved fluorescence spectroscopy. This study was stimulated by previous reports
Atanu Kumar Das et al.
The journal of physical chemistry. B, 115(16), 4680-4688 (2011-04-07)
Ultrafast photoinduced electron transfer (PET) from N,N-dimethylaniline (DMA) to coumarin dyes in a room-temperature ionic liquid (RTIL, [pmim][BF(4)]) and in a mixed micelle containing the RTIL and a triblock copolymer, (PEO)(20)-(PPO)(70)-(PEO)(20), (Pluronic P123) is studied using femtosecond upconversion. A Marcus-like

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