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等级
technical grade
质量水平
检测方案
90%
形式
powder
反应适用性
core: copper
reagent type: catalyst
mp
160 °C (dec.) (lit.)
SMILES字符串
[Cu+].[Cu+].c1ccccc1.[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F
InChI
1S/C6H6.2CHF3O3S.2Cu/c1-2-4-6-5-3-1;2*2-1(3,4)8(5,6)7;;/h1-6H;2*(H,5,6,7);;/q;;;2*+1/p-2
InChI key
GNXZWVVAAMVOJY-UHFFFAOYSA-L
应用
三氟甲磺酸铜(I)苯络合物可用作以下反应的催化剂:
它还可与基于氨基酸的手性膦配体结合使用,催化烷基锌与无环α,β-不饱和酮的不对称共轭加成,以高产率和优异的对映选择性合成β-烷基羰基。
- 通过形成羧酸铜(I)中间体,合成烯醇酯。
- 环状烯烃的对映选择性烯丙基氧化。
- 通过形成磺酰胺基自由基,由N-烯基、炔基和烷基N-苯甲酰氧基磺酰胺制备2,5-二取代的吡咯烷衍生物。
它还可与基于氨基酸的手性膦配体结合使用,催化烷基锌与无环α,β-不饱和酮的不对称共轭加成,以高产率和优异的对映选择性合成β-烷基羰基。
警示用语:
Warning
危险声明
危险分类
Flam. Sol. 2
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Thesis (2012)
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