所有图片(1)
About This Item
经验公式（希尔记法）:
C15H26N2O2
CAS号:
分子量:
266.38
Beilstein:
4190673
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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方案
99%
旋光性
[α]20/D −118°, c = 0.5 in chloroform
mp
51-53 °C (lit.)
官能团
ether
SMILES字符串
CC(C)(C)[C@H]1COC(CC2=N[C@H](CO2)C(C)(C)C)=N1
InChI
1S/C15H26N2O2/c1-14(2,3)10-8-18-12(16-10)7-13-17-11(9-19-13)15(4,5)6/h10-11H,7-9H2,1-6H3/t10-,11-/m1/s1
InChI key
WCCCBUXURHZPQL-GHMZBOCLSA-N
应用
2，2′-亚甲基双[（4S）-4-叔丁基-2-恶唑啉]（BOX配体）可以用作C2对称配体进行对映选择性不对称催化。由于恶唑啉氮对各种金属的强亲和力，它很容易形成双齿配位配合物。
对映选择性催化反应的 C2 对称配体由于噁唑啉氮具有对各种金属的强亲合性，因此可容易地形成双齿配位络合物。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
从最新的版本中选择一种：
分析证书(COA)
Lot/Batch Number
Heterogeneous bisoxazoline/copper complex: A green catalyst for the enantioselective reaction of nitromethane with substituted benzaldehydes
Maggi R, et al.
European Journal of Organic Chemistry, 2011(28), 5551-5554 (2011)
Selective oxidation of alkenes and alkynes catalyzed by copper complexes
Alvarez LX, et al.
Applied Catalysis A: General, 325(2), 303-308 (2007)
C 2-Symmetric bis (oxazolinato) lanthanide catalysts for enantioselective intramolecular hydroamination/cyclization
Hong S, et al.
Journal of the American Chemical Society, 125(48), 14768-14783 (2003)
Pfaltz, A.
Accounts of Chemical Research, 26, 339-339 (1993)
Gant, T.G. Meyers, A.I.
Tetrahedron, 50, 2297-2297 (1994)
商品
使用络合Cu(I)OTf的BOX配体进行不对称催化苯乙烯合成氮杂环丙烷的反应，BOX配体带苯基取代基的优于具有位阻需求的叔丁(t-Bu)基团。
BOX ligand complex enhances catalytic enantioselective aziridination of styrene, with phenyl substituents proving superior over t-Bu groups.
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